40-Fold Enhanced Intrinsic Proton Conductivity in Coordination Polymers with the Same Proton-Conducting Pathway by Tuning Metal Cation Nodes

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• 作者：Xuelian Su ; Zizhu Yao ; Yingxiang Ye ; Heng Zeng ; Gang Xu ; Ling Wu ; Xiuling Ma ; Qian-Huo Chen ; Lihua Wang ; Zhangjing Zhang ; Shengchang Xiang
• 刊名：Inorganic Chemistry
• 出版年：2016
• 出版时间：January 19, 2016
• 年：2016
• 卷：55
• 期：2
• 页码：983-986
• 全文大小：365K
• ISSN：1520-510X

文摘

Three isostructural imidazole-cation-templated metal phosphates (FJU-25) are the first examples to demonstrate that the tuning of metal cation nodes can be an efficient strategy to significantly improve the proton conductivity without changing the structure of the proton-conducting pathway.