文摘
Three-dimensional (3D) interconnected spherical graphene framework-decorated SnS nanoparticles (3D SnS@SG) is synthesized by self-assembly of graphene oxide nanosheets and positively charged polystyrene/SnO2 nanospheres, followed by a controllable in situ sulfidation reaction during calcination. The SnS nanoparticles with diameters of ∼10–30 nm are anchored to the surface of the spherical graphene wall tightly and uniformly. Benefiting from the 3D interconnected spherical graphene framework and subtle SnS nanoparticles, the generated Li2S could keep in close contact with Sn to make possible the in situ conversion reaction SnS + 2Li+ + 2e– ↔ Sn + Li2S. As a result, the 3D SnS@SG as the anode material for lithium ion batteries shows a high initial Coulombic efficiency of 75.3%. Apart from the irreversible capacity loss of 3D spherical graphene, the initial Coulombic efficiency of SnS in the 3D SnS@SG composite is as high as 99.7%, demonstrating the almost complete reversibility of Li2S in this system. Furthermore, it also exhibits an excellent reversible capacity (800 mAh g–1 after 100 cycles at 0.1 C and 527.1 mAh g–1 after 300 cycles at 1 °C) and outstanding rate capability (380 mAh g–1 at 5 °C).
