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• 作者：Natalya V. Izarova ; Michael H. Dickman ; Rosa Ngo Biboum ; Bineta Keita ; Louis Nadjo ; Vasanth Ramachandran ; Naresh S. Dalal ; Ulrich Kortz
• 刊名：Inorganic Chemistry
• 出版年：2009
• 出版时间：August 17, 2009
• 年：2009
• 卷：48
• 期：16
• 页码：7504-7506
• 全文大小：691K
• 年卷期：v.48,no.16(August 17, 2009)
• ISSN：1520-510X

文摘

Two discrete anionic palladium(II)−oxo clusters have been prepared: [Pd₁₃(As^VPh)₈O₃₂]⁶⁻ (1) and [Pd₁₃Se^IV₈O₃₂]⁶⁻ (2) were synthesized in one-pot self-assembly reactions of Pd(OAc)₂ with PhAsO₃H₂ and SeO₂ and characterized by single-crystal X-ray analysis, IR, thermogravimetric analysis, elemental analysis, magnetic and electron paramagnetic resonance measurements, and electrochemistry.