Desulfurization and H-Migration of Secondary Thioamides Catalyzed by an Iron Complex to Yield Imines and Their Reaction Mechanism

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• 作者：Kozo Fukumoto ; Akane Sakai ; Kazumasa Hayasaka ; Hiroshi Nakazawa
• 刊名：Organometallics
• 出版年：2013
• 出版时间：May 24, 2013
• 年：2013
• 卷：32
• 期：10
• 页码：2889-2892
• 全文大小：259K
• 年卷期：v.32,no.10(May 24, 2013)
• ISSN：1520-6041

文摘

Secondary thioamides were converted into imines as the major products using hydrosilane in the presence of an iron catalyst. An iron carbene complex with a silyl thiolato ligand was isolated as one of the intermediates of the catalytic cycle and was characterized by X-ray analysis.