Unusually Weak Metal-Hydrogen Bonds in HV(CO)4(P-P) and Their Effectiveness as H Donors
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文摘
The V-H bonds in HV(CO)4(P-P) are unusually weak (55 to 58 kcal/mol). They transfer Hes/entities/bull.gif"> to styrene more rapidly than CpCr(CO)3H does and are effective stoichiometric reagents for the cyclization of appropriate 1,6-dienes.
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