Rare-Earth Metal Alkyl and Hydride Complexes Stabilized by a Cyclen-Derived [NNNN] Macrocyclic Ancillary Ligand

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Rare-Earth Metal Alkyl and Hydride Complexes Stabilized by a Cyclen-Derived [NNNN] Macrocyclic Ancillary Ligand

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作者：Masato Ohashi ; Marcin Konkol ; Iker Del Rosal ; Romuald Poteau ; Laurent Maron ; Jun Okuda
刊名：Journal of the American Chemical Society
出版年：2008
出版时间：June 4, 2008
年：2008
卷：130
期：22
页码：6920 - 6921
全文大小：180K
年卷期：v.130,no.22(June 4, 2008)
ISSN：1520-5126

文摘

A trinuclear rare-earth metal hydride complex was synthesized from the dialkyl complex supported by a monoanionic [NNNN] macrocycle and shown to catalyze the hydrosilylation of olefins efficiently.