Incorporating Guest Molecules into Honeycomb Structures Constructed from Uranium(VI)-Polycarboxylates: Structural Diversities and Photocatalytic Activities for the Degradation of Organic Dye

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• 作者：Hao-Hong Li ; Xian-Hua Zeng ; Hong-Yan Wu ; Xiang Jie ; Shou-Tian Zheng ; Zhi-Rong Chen
• 刊名：Crystal Growth & Design
• 出版年：2015
• 出版时间：January 7, 2015
• 年：2015
• 卷：15
• 期：1
• 页码：10-13
• 全文大小：275K
• ISSN：1528-7505

文摘

Four uranium(VI)-polycarboxylates frameworks with honeycomb (6,3) nets have been assembled from solvothermal systems, which contain different guest molecules (transition metal complexes and methyl viologen). These compounds exhibit photocatalytic activities for the degradation of rhodamine B. Interestingly, the methyl viologen-containing one possesses the highest efficiency, which can be attributed to the electron acceptor nature of methyl viologen for the stabilization of active peroxide anions.