Kinetic Resolution in Asymmetric Epoxidation using Iminium Salt Catalysis

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Kinetic Resolution in Asymmetric Epoxidation using Iminium Salt Catalysis

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作者：Philip C. Bulman Page ; Louise F. Appleby ; Yohan Chan ; David P. Day ; Benjamin R. Buckley ; Alexandra M. Z. Slawin ; Steven M. Allin ; Michael J. McKenzie
刊名：The Journal of Organic Chemistry
出版年：2013
出版时间：August 16, 2013
年：2013
卷：78
期：16
页码：8074-8082
全文大小：385K
年卷期：v.78,no.16(August 16, 2013)
ISSN：1520-6904

文摘

The first reported examples of kinetic resolution in epoxidation reactions using iminium salt catalysis are described, providing up to 99% ee in the epoxidation of racemic cis-chromenes.