• 作者：Sean K. J. Devine ; David L. Van Vranken
• 刊名：Organic Letters
• 出版年：2008
• 出版时间：May 15, 2008
• 年：2008
• 卷：10
• 期：10
• 页码：1909 - 1911
• 全文大小：198K
• 年卷期：v.10,no.10(May 15, 2008)
• ISSN：1523-7052

Palladium catalysts are shown to catalyze the three-component coupling of vinyl halides, trimethylsilyldiazomethane, and stabilized carbon nucleophiles. The reaction is believed to proceed through a palladium-carbene intermediate LX(R)PdCHSiMe₃ that undergoes migration of the vinyl substituent to the electrophilic carbene center to generate an η³-allylpalladium intermediate. The allylpalladium intermediate is attacked by the carbon nucleophile to generate a vinylsilane product.