Template-Controlled Face-to-Face Stacking of Olefinic and Aromatic Carboxylic Acids in the Solid State

详细信息    查看全文

• 作者：Xuefeng Mei ; Shuanglong Liu ; Christian Wolf
• 刊名：Organic Letters
• 出版年：2007
• 出版时间：July 5, 2007
• 年：2007
• 卷：9
• 期：14
• 页码：2729 - 2732
• 全文大小：185K
• 年卷期：v.9,no.14(July 5, 2007)
• ISSN：1523-7052

文摘

ournals/orlef7/9/i14/figures/ol071039cn00002.gif" ALIGN="left" HSPACE=5>

A rigid 1,8-dipyridylnaphthalene template for supramolecular organization of unsaturated dicarboxylic acids in the solid state has been developed.Self-assembly of the template and aromatic dicarboxylic acids generates nondistorted paracyclophane and pyridinophane architectures withperfectly superimposed -systems. The dipyridyl template can be used to promote stereoselective solid-state dimerization of olefinic dicarboxylicacids.