[Ni(HF2)(3-Clpy)4]BF4 (py = pyridine): Evidence for Spin Exchange Along Strongly Distorted F路路路H路路路F鈥?/sup> Bridges in a One-Dimensional Polymeric Chain

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[Ni(HF2)(3-Clpy)4]BF4 (py = pyridine): Evidence for Spin Exchange Along Strongly Distorted F路路路H路路路F鈥?/sup> Bridges in a One-Dimensional Polymeric Chain

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作者：Jamie L. Manson ; Adora G. Baldwin ; Brian L. Scott ; Jesper Bendix ; Rico E. Del Sesto ; Paul A. Goddard ; Yoshimitsu Kohama ; Hope E. Tran ; Saman Ghannadzadeh ; John Singleton ; Tom Lancaster ; Johannes S. M枚ller ; Stephen J. Blundell ; Francis L. Pratt ; Vivien S. Zapf ; Jinhee Kang ; Changhoon Lee ; Myung-Hwan Whangbo ; Christopher Baines
刊名：Inorganic Chemistry
出版年：2012
出版时间：July 16, 2012
年：2012
卷：51
期：14
页码：7520-7528
全文大小：527K
年卷期：v.51,no.14(July 16, 2012)
ISSN：1520-510X

文摘

[Ni(HF₂)(3-Clpy)₄]BF₄ (py = pyridine) is a simple one-dimensional (1D) coordination polymer composed of compressed NiN₄F₂ octahedra that form chains with bridging HF₂^{鈥?/sup> ligands. In spite of significant distortion of the HF₂^{鈥?/sup> bridge, a quasi-1D antiferromagnetic (AFM) behavior was observed with J_FHF = 4.86 K.}}