Remarkable Effect of Iridium Cyclometalation on the Nonlinear Absorption Properties of a Quadrupolar Imine Ligand

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• 作者：Julien Massue ; Joanna Olesiak-Banska ; Erwann Jeanneau ; Christophe Aronica ; Katarzyna Matczyszyn ; Marek Samoc ; Cyrille Monnereau ; Chantal Andraud
• 刊名：Inorganic Chemistry
• 出版年：2013
• 出版时间：October 7, 2013
• 年：2013
• 卷：52
• 期：19
• 页码：10705-10707
• 全文大小：210K
• 年卷期：v.52,no.19(October 7, 2013)
• ISSN：1520-510X

文摘

A new type of dinuclear iridium complex, based on a quadrupolar Schiff base ligand, is synthesized and its structure fully characterized. Its linear and nonlinear spectroscopic properties are investigated, evidencing a strong contribution of the metal-to-ligand transitions not only to the linear absorption but also to the two- and three-photon absorption properties.