Temperature-Responsive Switch Constructed from an Anthracene-Functionalized Pillar[5]arene-Based Host–Guest System

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• 作者：Jiahai Bi ; Xiangfei Zeng ; Demei Tian ; Haibing Li
• 刊名：Organic Letters
• 出版年：2016
• 出版时间：March 4, 2016
• 年：2016
• 卷：18
• 期：5
• 页码：1092-1095
• 全文大小：337K
• ISSN：1523-7052

文摘

A monofunctionalized anthracene pillar[5]arene (MAP5) was designed and synthesized by a click reaction. MAP5 was bound to an ionic liquid through host–guest interactions to modify a gold interface. The bonding and release of MAP5 was readily and reversibly controlled by temperature regulation. The developed temperature-responsive switch at an interface can be used in memory storage, drug delivery, and sensing.