Adipate and Citrate Esters as Plasticizers for Poly(Lactic Acid)/Thermoplastic Starch Sheets

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• 作者：Marianne Ayumi Shirai (1) (2)
  Carmen Maria Olivera M眉ller (1)
  Maria Vict贸ria Eiras Grossmann (1)
  Fabio Yamashita (1)
  
  1. Department of Food Science and Technology ; Universidade Estadual de Londrina ; Rodovia Celso Garcia Cid (PR 445) ; km 380 ; P. O. Box 10011 ; Londrina ; PR ; CEP 86057-970 ; Brazil
  2. Universidade Tecnol贸gica Federal do Paran谩 ; Via Rosalina Maria dos Santos ; 1233 ; P.O. Box 271 ; Campo Mour茫o ; PR ; CEP 87031-899 ; Brazil
  
• 关键词：Extrusion ; Calendering ; Mechanical properties ; Glass transition ; Crystallinity ; Biodegradable polymer
• 刊名：Journal of Polymers and the Environment
• 出版年：2015
• 出版时间：March 2015
• 年：2015
• 卷：23
• 期：1
• 页码：54-61
• 全文大小：861 KB
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• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Polymer Sciences
  
• 出版者：Springer Netherlands
• ISSN：1572-8900

文摘

Poly(lactic acid) (PLA) and thermoplastic starch (TPS) sheets plasticized with different adipate and citrate esters were produced by a calendering-extrusion process. The incorporation of plasticizers significantly reduced the glass transition temperature and increased the PLA chain mobility thus improving the mechanical properties. Among the plasticizers employed, diethyl adipate significantly increased the elongation of the sheets and slightly increased the water vapor permeability. Micrographs revealed the incompatibility between starch and PLA, and there was no plasticizer phase separation, suggesting that the plasticizer concentration was adequate. The incorporation of adipate or citrate esters improves the mechanical properties and processability of PLA/TPS sheets produced by calendering extrusion at a pilot scale.