Structure and supramolecular organization of tri-m class="a-plus-plus">nm>-butyl(octadecyl)phosphonium tetrafluoroborate and its influence on catalytic activity of stabilized palladium nanoparticles

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• 作者：D. M. Arkhipova ; V. V. Ermolaev ; V. A. Miluykov…
• 关键词：phosphonium salts ; palladium nanoparticles ; stabilization ; catalysis ; Suzuki reaction ; aggregation
• 刊名：Russian Chemical Bulletin
• 出版年：2015
• 出版时间：October 2015
• 年：2015
• 卷：64
• 期：10
• 页码：2486-2492
• 全文大小：1,469 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Chemistry
  Organic Chemistry
  Inorganic Chemistry
  Russian Library of Science
  
• 出版者：Springer New York
• ISSN：1573-9171
• 卷排序：64

文摘

A crystal structure and aggregation properties of tri-n-butyl(octadecyl)phosphonium tetrafluoroborate were studied. Palladium nanoparticles stabilized by this phosphonium salt exhibit different catalytic activity in the Suzuki reaction, depending on the concentration of the stabilizing agent, which is related to the supramolecular organization of the Pd–phosphonium salt system.