Role of the chemical mechanism in the temperature dependence of the rate of gas combustion reactions

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• 作者：V. V. Azatyan (1)
  
  1. Institute of Structural Macrokinetics and Materials Research Problems ; Russian Academy of Sciences ; Chernogolovka ; Moscow oblast ; 142432 ; Russia
  
• 刊名：Kinetics and Catalysis
• 出版年：2015
• 出版时间：January 2015
• 年：2015
• 卷：56
• 期：1
• 页码：1-11
• 全文大小：233 KB
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• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Physical Chemistry
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1608-3210

文摘

The determining role of the kinetic mechanism in the temperature dependence of reaction rates is demonstrated. New evidence is presented to prove that the branched chain nature of gas combustion at low pressures and under isothermal conditions, discovered by N.N. Semenov, persists in combustion processes at elevated pressures under any temperature and macrokinetic conditions. It is noted that the temperature dependence of the rate constants of bimolecular reactions weakens with an increasing activation energy.