Chain nature of the combustion, explosion, and detonation of gases: New aspects of theory

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• 作者：V. V. Azatyan
• 关键词：combustion ; explosion ; detonation ; mechanisms of processes ; aspects of theory
• 刊名：Russian Journal of Physical Chemistry A, Focus on Chemistry
• 出版年：2015
• 出版时间：November 2015
• 年：2015
• 卷：89
• 期：11
• 页码：1997-2005
• 全文大小：606 KB
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• 作者单位：V. V. Azatyan (1)
  
  1. Institute of Structural Macrokinetics and Problems of Material Science, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Physical Chemistry
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1531-863X

文摘

It is shown that contrary to previous concepts, the gas-phase processes of combustion occur via branched-chain mechanisms not only at extremely low pressures with no change in temperature, but at atmospheric and elevated pressures in any temperature mode. Based on the theory of nonisothermic chain processes, an explanation of the ignition, flame propagation, explosion, and detonation of gases is obtained experimentally in ranges of pressure and temperature important to engineering. Chemical methods for controlling the above modes of combustion are developed. Keywords combustion explosion detonation mechanisms of processes aspects of theory