Structural Features and Catalytic Properties of Pt/CeO₂ Catalysts Prepared by Modified Reduction‐Deposition Techniques

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• 作者：Tang ; Xiaolan ; Zhang ; Baocai ; Li ; Yong ; Xu ; Yide ; Xin ; Qin ; Shen ; Wenjie
• 关键词：complete oxidation ; DME ; HCHO liquid phase reduction ; modified polyol method ; Pt/CeO2
• 刊名：Catalysis Letters
• 出版年：2004
• 出版时间：2004
• 年：2004
• 卷：97
• 期：3/4
• 页码：163-169
• 全文大小：218 KB

文摘

The structural features and catalytic properties of Pt/CeO₂ catalysts prepared by liquid phase reduction‐deposition techniques with formaldehyde and ethylene glycol as reducing agents, respectively, were investigated. TPR and CO pulse titration measurements revealed that smaller particle size and uniform dispersion of platinum were achieved by modified polyol preparation process, which is beneficial to generate appropriate Pt–O–Ce chemical bonding. XPS analysis further demonstrated the presence of strong metal‐support interaction in above Pt/CeO₂catalyst. It was observed that the reducing ability and the solvent effect play important roles in controlling the formation of nuclei as well as its growth rate. The sample prepared by modified polyol method exhibited higher catalytic activities and longer stability for the complete oxidation of dimethyl ether than Pt/CeO₂catalyst prepared by HCHO liquid phase reduction.