Characterization of natural zeolite clinoptilolite for sorption of contaminants
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  • 作者:E. Xingu-Contreras ; G. García-Rosales ; I. García-Sosa…
  • 关键词:Natural zeolites ; Nanomaterials ; M?ssbauer spectroscopy ; Sorption
  • 刊名:Hyperfine Interactions
  • 出版年:2015
  • 出版时间:June 2015
  • 年:2015
  • 卷:232
  • 期:1-3
  • 页码:7-18
  • 全文大小:1,077 KB
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  • 作者单位:E. Xingu-Contreras (1)
    G. García-Rosales (1)
    I. García-Sosa (2)
    A. Cabral-Prieto (2)
    M. Solache-Ríos (2)

    1. Instituto Tecnológico de Toluca, Avenida Tecnológico S/N, Fraccionamiento. La Virgen, C. P. 52149, Metepec, Estado de México, México
    2. Departamento de Química, Instituto Nacional de Investigaciones Nucleares, Apdo. Postal 18-1027, Col. Escandón, Deleg. M. Hidalgo, C. P. 11801, México D. F., México
  • 刊物类别:Physics and Astronomy
  • 刊物主题:Physics
    Nuclear Physics, Heavy Ions and Hadrons
    Atoms, Molecules, Clusters and Plasmas
    Condensed Matter
    Surfaces and Interfaces and Thin Films
  • 出版者:Springer Netherlands
  • ISSN:1572-9540
文摘
The nanoparticles technology has received considerable attention for its potential applications in groundwater treatment for the removal of various pollutants as Cadmium. In this work, iron boride nanoparticles were synthesized in pure form and in presence of homo-ionized zeolite clinoptilolite, as support material. These materials were used for removing Cd (II) from aqueous solutions containing 10, 50, 100, 150, 200, 250, 300 and 400 mg/L. The characterization of these materials was made by using X-ray Diffraction, Scanning Electron Microscopy and M?ssbauer Spectroscopy. Pure iron boride particles show a broad X-ray diffraction peak centered at 45?/sup> (2?? inferring the presence of nanocrystals of Fe2B as identified from M?ssbauer Spectroscopy. The size of these Fe2B particles was within the range of 50 and 120 nm. The maximum sorption capacities for Cd (II) of iron boride particles and supported iron boride particles in homo-ionized zeolitic material were nearly 100 %. For homo-ionized zeolite and homo-ionized zeolite plus sodium borohydride was ?95 %.
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