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Synthesis and study of calixarene-doped polypyrrole-TiO2/ZnO composites: Antimicrobial activity and electrochemical sensors
- 作者:Babasaheb J. Waghmode ; Zahid Husain ; Meenal Joshi…
- 关键词:Polypyrrole ; Calixarene ; ZnO ; TiO2 ; Electrochemical sensor ; Antimicrobial activity
- 刊名:Journal of Polymer Research
- 出版年:2016
- 出版时间:February 2016
- 年:2016
- 卷:23
- 期:2
- 全文大小:2,472 KB
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- 作者单位:Babasaheb J. Waghmode (1) (2)
Zahid Husain (1) Meenal Joshi (3) Shivaram D. Sathaye (4) Kashinath R. Patil (2) Dipalee D. Malkhede (1)
1. Department of Chemistry, Savitribai Phule Pune University, Pune, 411007, India 2. National Chemical Laboratory, Dr. Homi Bhabha Road, Pashan, Pune, 411008, India 3. Late Prin. B. V. Bhide Foundation Research Institute, Pune, 411030, India 4. 759/83 Deccan Gymkhana, Pune, 411004, India
- 刊物类别:Chemistry and Materials Science
- 刊物主题:Chemistry
Polymer Sciences Industrial Chemistry and Chemical Engineering Characterization and Evaluation Materials
- 出版者:Springer Netherlands
- ISSN:1572-8935
文摘
The present communication describes the synthesis of an electroactive nanocomposite of calixarene-doped polypyrrole (PPY) containing an oxide of Ti/Zn. The additive TiO2/ZnO serves as an oxidizing agent for the polymerization, thus avoiding the use of hazardous organic solvents while calixarene doping stabilizes the polymer. The materials synthesized herein were characterized by UV-visible spectroscopy, FT-IR spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), X-ray photoelectron spectroscopy (XPS), and cyclic voltammetry (CV) of synthesized nanocomposites. It was revealed that the resulting calixarene-doped polypyrrole-TiO2/ZnO nanocomposite has (1) long-time stability, (2) significant electrochemical activity for sensing formaldehyde, and (3) good antimicrobial activity.
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