Synthesis and reactivity of metal-containing monomers

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• 作者：B. A. Komarov ; A. T. Kapasharov ; E. A. Dzhavadyan…
• 关键词：copper azomethine complexes ; chelate complexes ; epoxy resin ; metal ; containing epoxy polymers ; polymer modification
• 刊名：Russian Chemical Bulletin
• 出版年：2015
• 出版时间：April 2015
• 年：2015
• 卷：64
• 期：4
• 页码：936-942
• 全文大小：285 KB
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• 作者单位：B. A. Komarov (1)
  A. T. Kapasharov (1)
  E. A. Dzhavadyan (1)
  V. A. Lesnichaya (1)
  G. I. Dzhardimalieva (1)
  A. S. Burlov (2)
  A. I. Uraev (2)
  S. A. Mashchenko (2)
  D. A. Garnovskii (3)
  A. D. Pomogailo (1)
  
  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation
  2. Research Institute of Physical and Organic Chemistry, Southern Federal University, 194/2 prosp. Stachki, 344090, Rostov-on-Don, Russian Federation
  3. Southern Scientific Center, 41 ul. Chekhova, 344006, Rostov-on-Don, Russian Federation
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Chemistry
  Organic Chemistry
  Inorganic Chemistry
  Russian Library of Science
  
• 出版者：Springer New York
• ISSN：1573-9171

文摘

The effect of additives of copper azomethine complexes of different structure on the character of polycondensation and physicomechanical properties of the obtained metal-containing epoxy polymers was studied. It was shown by the DSC method that the thermal stability of the starting CuII azomethine complexes depended on their structure and nature of polar functional groups. The physicomechanical properties of the unmodified and modified epoxyamine polymers at different ratios of functional groups were compared. The additives of CuII azomethine complexes of 0.42-.43 wt.% were shown to increase the impact strength of the polymers at the ratio [NH]/EG = 1.07-.13 (EG is epoxy group). Key words copper azomethine complexes chelate complexes epoxy resin metal-containing epoxy polymers polymer modification