Effect of chain length on the wetting properties of alkyltrichlorosilane coated cellulose-based paper

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Effect of chain length on the wetting properties of alkyltrichlorosilane coated cellulose-based paper

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作者：Zhenguan Tang ; Hanyang Li ; Dennis W. Hess ; Victor Breedveld
关键词：Alkyltrichlorosilane ; Water repellency ; Superhydrophobic surface ; Methyltrimethoxysilane ; Octadecyltrichlorosilane
刊名：Cellulose
出版年：2016
出版时间：April 2016
年：2016
卷：23
期：2
页码：1401-1413
全文大小：1,938 KB
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作者单位：Zhenguan Tang (1) (2)
Hanyang Li (1)
Dennis W. Hess (1) (2)
Victor Breedveld (1) (2)

1. School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Drive NW, Atlanta, GA, 30332, USA
2. Renewable Bioproducts Institute, Georgia Institute of Technology, 500 10th Street NW, Atlanta, GA, 30318, USA
刊物类别：Chemistry and Materials Science
刊物主题：Chemistry
Bioorganic Chemistry
Physical Chemistry
Organic Chemistry
Polymer Sciences
出版者：Springer Netherlands
ISSN：1572-882X

文摘

The effect of alkyl chain length on the wetting properties of alkyltrichlorosilane coated cellulose-based paper is reported for four different reagents: methyltrichlorosilane (MTCS; –CH₃), butyltrichlorosilane (BTCS; –C₄H₉), dodecyltrichlorosilane (DTCS; –C₁₂H₂₅) and octadecyltrichlorosilane (OTCS; –C₁₈H₃₇). SEM analysis reveals that by systematically varying alkyl chain length, films with different surface morphologies can be generated on flat silicon wafer control samples and on cellulose-based paper samples. The variation in surface morphology leads to different wetting behavior, as determined by measuring static water and oil contact angles. Due to the nano- and micron- scale roughness on MTCS coated substrates, paper samples coated with MTCS display superhydrophobicity with a water contact angle of 152.2°, which is the highest water contact angle among these four alkyltrichlorosilanes. However, additional nano-scale roughness from MTCS coating reduces the oil resistance of coated paper samples, while paper samples coated with long-chain alkyltrichlorosilanes have lower surface energy and also lack nano-scale roughness. As a result, paper samples coated with OTCS display the highest resistance against oils (ethylene glycol contact angle 125.5°; diiodomethane contact angle 101.3°). The intrinsic porosity of paper is largely retained after coating, as indicated by the fact that low surface tension fluids like methanol can easily penetrate coated paper samples.