The Redox Functions of Metallodendrimers

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• 作者：Didier Astruc ; Jaime Ruiz
• 关键词：Dendrimer ; Electron transfer ; Redox catalysis ; Biosensor ; Battery ; Molecular recognition
• 刊名：Journal of Inorganic and Organometallic Polymers and Materials
• 出版年：2015
• 出版时间：January 2015
• 年：2015
• 卷：25
• 期：1
• 页码：2-11
• 全文大小：1,122 KB
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• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Inorganic Chemistry
  Organic Chemistry
  Polymer Sciences
  
• 出版者：Springer New York
• ISSN：1574-1451

文摘

This mini-review article focuses on metallodendrimers containing redox-robust systems that are attached to branches at the dendrimer periphery, and specifically on the properties, functions and applications of these nano-materials. The mini-review is illustrated essentially with the dendrimers containing metal-sandwich termini such as ferrocenes, cobaltocenes and mixed-sandwich complexes of the [FeCp(η6-arene)] family that have been developed in the author’s laboratory. Synthetic aspects have been developed and reviewed elsewhere, and here emphasis is placed on stoichiometric and catalytic electron-transfer processes involving redox recognition, redox sensing, redox catalysis and molecular materials aspects. Finally uses of redox metallocenes and metallocene-containing macromolecules as components of batteries are briefly discussed.