Controlled synthesis of multi-morphology Te crystals by a convenient Lewis acid/base-assisted solvothermal method

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• 作者：XiaoPing Wu (1)
  Lin Yuan (2)
  ShaoMin Zhou (1) shaominzhou@yahoo.com
  ShiYun Lou (1)
  YongQiang Wang (1)
  Tao Gao (1)
  YuBiao Liu (1)
  XiaoJing Shi (1)
• 关键词：Nanostructure &#8211 ; Tellurium &#8211 ; Lewis acid/base &#8211 ; Solvothermal
• 刊名：Journal of Nanoparticle Research
• 出版年：2012
• 出版时间：August 2012
• 年：2012
• 卷：14
• 期：8
• 全文大小：764.0 KB
• 参考文献：1. Baughman RH, Zakhidov AA, de Heer WA (2002) Carbon nanotubes–the route toward applications. Science 297:787–792
  2. Beauvais J, Lessard RA, Galarneau P, Knystautas EJ (1990) Self-developing holographic recording in li-implanted Te thin-films. Appl Phys Lett 57:1354–1356
  3. Cui Y, Lieber CM (2001) Functional nanoscale electronic devices assembled using silicon nanowire building blocks. Science 291:851–853
  4. Engelhard T, Jones ED, Viney I, Mastai Y, Hodes G (2000) Deposition of tellurium films by decomposition of electrochemically-generated H2Te: application to radiative cooling devices. Thin Solid Films 370:101–105
  5. Fukui T, Ohara S, Naito M, Noqi K (2001) Morphology control of the electrode for solid oxide fuel cells by using nanoparticles. J Nanopart Res 3:171–174
  6. Gautam UK, Rao CNR (2004) Controlled synthesis of crystalline tellurium nanorods, nanowires, nanobelts and related structures by a self-seeding solution process. J Mater Chem 14:2530–2535
  7. Geng BY, Lin Y, Peng XS, Meng GW, Zhang LD (2003) Large-scale synthesis of single-crystalline Te nanobelts by a low-temperature chemical vapour deposition route. Nanotechnology 14:983–986
  8. Guo YG, Li CJ, Wan LJ, Chen DM, Wang CR, Bai CL, Wang YG (2003) Well-defined fullerene nanowire arrays. Adv Funct Mater 13:626–630
  9. Han JT, Huang YH, Wu XJ, Wu CL, Wei W, Peng B, Huang W, Goodenough JB (2006) Tunable synthesis of bismuth ferrites with various morphologies. Adv Mater 18:2145–2418
  10. He ZB, Yu SH, Zhu JP (2005) Amino acids controlled growth of shuttle-like scrolled tellurium nanotubes and nanowires with sharp tips. Chem Mater 17:2785–2788
  11. Li XL, Cao GH, Feng CM, Li YD (2004) Synthesis and magnetoresistance measurement of tellurium microtubes. J Mater Chem 14:244–247
  12. Liu Z, Searson PC (2006) Single nanoporous gold nanowire sensors. J Phys Chem B 110:4318–4322
  13. Liu ZP, Li S, Yang Y, Hu ZK, Peng S, Liang JB, Qian YT (2003) Shape-controlled synthesis and growth mechanism of one-dimensional nanostructures of trigonal tellurium. New J Chem 27:1748–1752
  14. Liu ZP, Hu ZK, Liang JB, Li S, Yang Y, Peng S, Qian YT (2004) Size-controlled synthesis and growth mechanism of monodisperse tellurium nanorods by a surfactant-assisted method. Langmuir 20:214–218
  15. Lriarte GF (2011) Large scale synthesis of silicon nanowires. J Nanopart Res 13:1737–1745
  16. Lu QY, Gao F, Komarneni S (2004) Biomolecule-assisted reduction in the synthesis of single-crystalline tellurium nanowires. Adv Mater 16:1629–1632
  17. Mayers B, Xia YN (2002a) One-dimensional nanostructures of trigonal tellurium with various morphologies can be synthesized using a solution-phase approach. J Mater Chem 12:1875–1881
  18. Mayers B, Xia YN (2002b) Formation of tellurium nanotubes through concentration depletion at the surfaces of seeds. Adv Mater 14:279–282
  19. Mo MS, Zeng JH, Liu XM, Yu WC, Zhang SY, Qian YT (2002) Controlled hydrothermal synthesis of thin single-crystal tellurium nanobelts and nanotubes. Adv Mater 14:1658–1662
  20. Sahoo AK, Srivastava SK (2011) Morpholine-4-carbodithioate Se and Te complex as single source precursor for synthesis of Se and Te with diverse morphologies. Cryst Growth Des 11:1597–1606
  21. Schmidt V, Gǒsele U (2007) How nanowires grow. Science 316:698–699
  22. She GW, Shi WS, Zhang XH, Wong TL, Cai Y, Wang N (2009) Template-free electrodeposition of one-dimensional nanostructures of Tellurium. Cryst Growth Des 9:663–666
  23. Shen GZ, Chen D, Tang KB, Qian YT (2004) Self-sacrificing template route to novel patterns of radially aligned Bi2(Se, S)3 nanorods and Bi2Se3 flakes. Nanotechnology 15:1530–1534
  24. Sinha S, Gao B, Zhou O (2004) Synthesis of silicon nanowires and novel nano-dendrite structures. J Nanopart Res 6:421–425
  25. Song JM, Lin YZ, Zhan YJ, Tian YC, Liu G, Yu SH (2008) Superlong high-quality tellurium nanotubes: synthesis, characterization, and optical property. Cryst Growth Des 8:1902–1908
  26. Souilhac D, Billerey D, Gundjian A (1990) Infrared 2-dimensional acoustooptic deflector using a tellurium crystal. Appl Opt 29:1798–1804
  27. Sun YG, Yin YD, Mayers BT, Herricks T, Xia YN (2002) Uniform silver nanowires synthesis by reducing AgNO3 with ethylene glycol in the presence of seeds and poly(vinyl pyrrolidone). Chem Mater 14:4736–4745
  28. Tang ZY, Wang Y, Sun K, Kotov NA (2005) Spontaneous transformation of stabilizer-depleted binary semiconductor nanoparticles into selenium and tellurium nanowires. Adv Mater 17:358–363
  29. Venables JA (2000) Introduction to surface and thin film processes. Cambridge University Press, Cambridge
  30. Wang YW, Zhang LD, Meng GW, Peng XS, Jin YX, Zhang J (2002) Fabrication of ordered ferromagnetic-nonmagnetic alloy nanowire arrays and their magnetic property dependence on annealing temperature. J Phys Chem B 106:2502–2507
  31. Wang JW, Wang X, Peng Q, Li YD (2004) Synthesis and characterization of bismuth single-crystalline nanowires and nanospheres. Inorg Chem 43:7552–7556
  32. Wang X, Zhuang J, Peng Q, Li YD (2005) A general strategy for nanocrystal synthesis. Nature 437:121–124
  33. Wang Q, Jiang CL, Yu CF, Chen QW (2007) General solution-based route to V-VI semiconductors nanorods from hydrolysate. J Nanopart Res 9:269–274
  34. Wang S, Guan WP, Ma DK, Chen X, Wan L, Huang SM, Wang JC (2010a) Synthesis, characterization and optical properties of flower-like tellurium. CrystEngComm 12:166–171
  35. Wang S, Zhang KJ, Zhou HA, Guan WP, Ma DK, Lin JJ, Zhang LJ, Huang SM, Wang JC (2010b) Large-scale synthesis of feather-like single-crystal Te via a biphasic interfacial reaction route. CrystEngComm 12:3852–3857
  36. Wei GD, Yuan DB, Lin YH, Nan CW (2003) Solvothermal synthesis of porous tellurium nanotubes. Chem Phys Lett 372:590–594
  37. Wu YY, Yang PD (2000) Germanium nanowire growth via simple vapor transport. Chem Mater 12:605–607
  38. Xi GC, Peng YY, Yu WC, Qian YT (2005) Synthesis, characterization, and growth mechanism of tellurium nanotubes. Cryst Growth Des 5:325–328
  39. Yi GC, Wang CR, Park WI (2005) ZnO nanorods: synthesis, characterization and applications. Semicond Sci Technol 20:S22–S34
  40. Yu DB, Jiang T, Wang F, Wang ZR, Wang Y, Shi W, Sun XQ (2009) Controlled growth of multi-morphology hexagonal t-Se microcrystals: tubes, wires, and flowers by a convenient Lewis acid-assisted solvothermal method. CrystEngComm 11:1270–1274
  41. Zhang B, Dai W, Ye X, Zuo Z, Xie Y (2006) Photothermally assisted solution-phase synthesis of microscale tubes, rods, shuttles, and an urchin-like assembly of single-crystalline trigonal selenium. Angew Chem Int Ed 45:2571–2574
  42. Zhang LH, Yang HQ, Yu J, Shao FH, Li L, Zhang FH, Zhao H (2009) Controlled synthesis and photocatalytic activity of ZnSe nanostructured assemblies with different morphologies and crystalline phases. J Phys Chem C 113:5434–5443
  43. Zhu YJ, Wang WW, Qi RJ, Hu XL (2004) Microwave-assisted synthesis of single-crystalline tellurium nanorods and nanowires in ionic liquids. Angew Chem Int Ed 43:1410–1414
  44. Zhu HT, Zhang H, Liang JK, Rao GH, Li JB, Liu GY, Du ZM, Fan HM, Luo J (2011) Controlled synthesis of Tellurium nanostructures from nanotubes to nanorods and nanowires and their template applications. J Phys Chem C 115:6375–6380
• 作者单位：1. Key Lab for Special Functional Materials of Ministry of Education, Henan University, Kaifeng, 475004 People鈥檚 Republic of China2. Department of Biology and Chemistry, Hunan University of Science and Engineering, Yongzhou, 425100 Hunan, People鈥檚 Republic of China
• ISSN：1572-896X

文摘

This paper reports on the controlled growth of multi-morphology Te crystals by a convenient Lewis acid/base-assisted solvothermal method for the first time. The morphological transformation from one-dimension (1D) nanostructures to 2D hierarchical flowerlike microarchitecture has been observed. The nanorods and nanowires with a well-defined crystallographical structure and the hierarchical flowers microarchitecture were obtained by changing the Lewis acids/bases. Lewis acids/bases were found to be crucial for the formation of the products by not only acting as the pH regulator but also as the shape controller, owing to their hydrolysis in the solvent to in situ form H+/OH− and hydrates. The results suggest that this should be an effective approach to the control the growth of t-Te crystals with interesting multiple morphologies, which are of interest for both theoretical investigations and practical applications.