Microstructure and superconducting properties of (BaTiOb class="a-plus-plus">3b>, Yb class="a-plus-plus">2b>Ob class="a-plus-plus">3b>)-doped YBCO films under different firing temperatures
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文摘
YBab>2b>Cub>3b>Ob>7−xb> (YBCO) films with co-doping of BaTiOb>3b> (BTO) and Yb>2b>Ob>3b> nanostructures were successfully fabricated on LaAlOb>3b> (LAO) substrate by metal organic deposition using trifluoroacetates (TFA-MOD). The focus of this study was to optimize the process conditions during the firing heat treatment of high critical current density (Jb>Cb>)-co-doped YBCO films. The effect of the firing temperatures on both the surface morphology and the superconducting properties for the doped YBCO films was systematically studied. According to the X-ray diffraction (XRD) and scanning electron microscopy (SEM) results, the films prepared at 820 and 850 °C show poor electrical performance due to impurity phases and large pores. In contrast, the dense YBCO films prepared at 830 and 840 °C with the critical current densities of 10 MA·cm−2 (77 K, 0 T) are obtained.
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