A Polypyrrole/CoFe₂O₄/Hollow Glass Microspheres three-layer sandwich structure microwave absorbing material with wide absorbing bandwidth and strong absorbing capacity

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• 作者：Xingwei Wang ; Hongxia Yan ; Rong Xue…
• 刊名：Journal of Materials Science: Materials in Electronics
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：28
• 期：1
• 页码：519-525
• 全文大小：
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Optical and Electronic Materials; Characterization and Evaluation of Materials;
• 出版者：Springer US
• ISSN：1573-482X
• 卷排序：28

文摘

A new PPy/CoFe₂O₄/HGMs microwave absorbing composite particle with three-layer sandwich structure, comprising cobalt ferrite (CoFe₂O₄) and polypyrrole (PPy) coating on the surface of hollow glass microspheres (HGMs), was synthesized by the method of co-precipitation and in situ polymerization. The surface morphology, phase structure and chemical component of the composite had been characterized by scanning electron microscope and X-ray diffractometer. The results indicated HGMs were coated by CoFe₂O₄ completely and the obtained CoFe₂O₄/HGMs composites were warped by PPy. The conductivity and the saturation magnetization Ms of the resulting PPy/CoFe₂O₄/HGMs composites are 0.09 S/cm and 46 emu/g, respectively. The vector network analyzer showed the composite performed better microwave absorption ability than that of PPy and PPy/HGMs. The reflection loss of the composite with 2.58 mm thickness is more than−10 dB which means over 90 % microwave is absorbed in X-band (8.38–12.4 GHz). The ternary composite that has light weight, wide absorbing bandwidth, strong absorbing capacity and conductivity can be an attractive candidate in the field of microwave absorption.