Surface grafting of reduced graphene oxide using nanocrystalline cellulose via click reaction

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• 作者：Roya Kabiri (1)
  Hassan Namazi (1) (2)
  
• 关键词：Graphene ; Reduced graphene oxide ; Nanocrystalline cellulose ; Click reaction
• 刊名：Journal of Nanoparticle Research
• 出版年：2014
• 出版时间：July 2014
• 年：2014
• 卷：16
• 期：7
• 全文大小：
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• 作者单位：Roya Kabiri (1)
  Hassan Namazi (1) (2)
  
  1. Research Laboratory of Dendrimers and Nanopolymers, Faculty of Chemistry, University of Tabriz, P.O. Box: 51666, Tabriz, Iran
  2. Research Center for Pharmaceutical Nanonotechnology, Tabriz University of Medical Sciences, Tabriz, Iran
  
• ISSN：1572-896X

文摘

Reduced graphene oxide (RGO) sheet was functionalized with nanocrystalline cellulose (NCC) via click coupling between azide-functionalized graphene oxide (GO-N3) and terminal propargyl-functionalized nanocrystalline cellulose (PG-NCC). First, the reactive azide groups were introduced on the surface of GO with azidation of 2-chloroethyl isocyanate-treated graphene oxide (GO-Cl). Then, the resulted compounds were reacted with PG-NCC utilizing copper-catalyzed azide-alkyne cycloaddition. During the click reaction, GO was simultaneously reduced to graphene. The coupling was confirmed by Fourier transform infrared, Raman, DEPT135, and 13C NMR spectroscopy, and the complete exfoliation of graphene in the NCC matrix was confirmed with X-ray diffraction measurement. The degree of functionalization from the gradual mass loss of RGO-NCC suggests that around 23 mass?% has been functionalized covalently. The size of both NCC and GO was found to be in nanometric range, which decreased after click reaction.