Crystal Structure and Magnetic Property of a 2-D Hexa-Circular Ring Cu(II)/Na(I)-Substituted Sandwich-Type Arsenotungstate

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• 作者：Jiai Hua (1)
  Xiang Ma (1)
  Pengtao Ma (1)
  Jingping Wang (1)
  Jingyang Niu (1)
  
• 关键词：Polyoxometalates ; Arsenotungstate ; Sandwich ; type ; {Cu5Na} hexagon moiety
• 刊名：Journal of Cluster Science
• 出版年：2013
• 出版时间：September 2013
• 年：2013
• 卷：24
• 期：3
• 页码：689-700
• 全文大小：614KB
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• 作者单位：Jiai Hua (1)
  Xiang Ma (1)
  Pengtao Ma (1)
  Jingping Wang (1)
  Jingyang Niu (1)
  
  1. Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475004, People’s Republic of China
  

文摘

A new compound H8[NaCu5Cl(H2O)3(B-α-AsW9O33)2] 24H2O (1) is synthetized by the reaction of the CuCl2 2H2O and Na27[NaAs4W40O140] 60H2O in aqueous solution, which is constructed from a {Cu5Na} hexagon moiety sandwiched by two trilacunary [B-α-AsW9O33]9?/sup> units. The structure is determined by single-crystal X-ray diffraction technique and further characterized by IR spectroscopy. Single-crystal X-ray diffraction analysis reveals that 1 is built by two trilacunary [B-α-AsW9O33]9?/sup> units incorporating a {Cu5Na} hexagon moiety and further linked to each other to form an infinitely extended 2-D network via Cu–O–W bridges. Notably, magnetic measurement demonstrates that the occurrence of intramolecular ferromagnetic Cu–Cu interactions within {Cu5Na} hexagon moiety.