Synthesis, structural characterization and hydrogen storage of nickel-containing mesoporous MCM-48 by electroless plating

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• 作者：Guangxu Zhang 张光旭 ; Xiaocong Ren ; Yuan Fang…
• 关键词：MCM ; 48 ; electroless Ni ; plating ; ultrasonic method ; metallic composites ; hydrogen storage
• 刊名：Journal of Wuhan University of Technology--Materials Science Edition
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：31
• 期：1
• 页码：64-67
• 全文大小：1,227 KB
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• 作者单位：Guangxu Zhang 张光旭 (1)
  Xiaocong Ren (2)
  Yuan Fang (1)
  Jian Chen (1)
  
  1. School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, Wuhan, 430070, China
  2. Department of Biotechnology, ZhiXing College of HuBei University, Wuhan, 430070, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Materials Science
  Chinese Library of Science
  
• 出版者：Wuhan University, co-published with Springer
• ISSN：1993-0437

文摘

Hydrogen is a promising fuel for it is clean, highly abundant and non-toxic, but on-board storage of hydrogen is still a challenge. So it is imperative to have an efficient method of hydrogen storage. The mesoporous MCM-48 especially the nickel-containing MCM-48 has great potential in hydrogen storage. MCM- 48 was prepared by hydrothermal synthesis. Then electroless plating technology was used to deposit Ni on the surface of MCM-48 under ultrasonic environment. Powder X-ray diffraction (XRD), transmission electron microscopy (TEM), and N₂ adsorption-desorption were employed to investigate the pore structure properties. The results showed that all the samples had Ia3d cubic structure and pore channels were highly ordered. Hydrogen adsorption studies showed that the MCM-48 after nickel plating adsorbed nearly twice the amount of hydrogen than pure MCM-48 at 2.0 MPa, 263 K. So we believe that a small amount of Ni can improve the capacity of hydrogen adsorption of MCM-48 efficiently. Key words MCM-48 electroless Ni-plating ultrasonic method metallic composites hydrogen storage