Synthesis and characterization of four novel 2-(trimethylsilyl)ethyl glycosides

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• 作者：Huanhuan Qu (1) (2) (3)
  Wenji Sun (3)
  Tao Sun (4)
  Matthieu Sollogoub (1)
  Yongmin Zhang (1)
  
  1. Institut Parisien de Chimie Mol茅culaire (UMR CNRS 7201) ; Universit茅 Pierre et Marie Curie-Paris 6 ; C.181 ; 4 Place Jussieu ; 75005 ; Paris ; France
  2. Glycochemistry & Glycobiology Lab ; Shanghai Institute of Materia Medica ; Chinese Academy of Sciences ; 555 Zu Chong Zhi Road ; Pudong ; Shanghai ; 201203 ; People鈥檚 Republic of China
  3. Biomedicine Key Laboratory of Shaanxi Province ; Northwest University ; Xi鈥檃n ; 710069 ; People鈥檚 Republic of China
  4. Key Laboratory of Colloid and Interface Chemistry ; Ministry of Education ; School of Chemistry and Chemical Engineering ; Shandong University ; Jinan ; 250100 ; People鈥檚 Republic of China
  
• 关键词：Total synthesis ; Structure elucidation ; Glycosides ; NMR spectroscopy ; Oligosaccharides
• 刊名：Research on Chemical Intermediates
• 出版年：2015
• 出版时间：February 2015
• 年：2015
• 卷：41
• 期：2
• 页码：1107-1113
• 全文大小：204 KB
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• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Physical Chemistry
  Inorganic Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1568-5675

文摘

Four novel 2-(trimethylsilyl)ethyl glycosides have been synthesized by a short and efficient route starting from d-glucose. Their structures were elucidated by applying high-resolution mass spectra, and one-dimensional and two-dimensional NMR techniques. These glycosides were prepared and used as intermediate building blocks in the scheme developed for oligosaccharide construction.