Preparation, crystal structure and thermal studies of cadmium perchlorate complex with 2,2-bipyridine

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• 作者：Chandra Prakash Singh ; Abhishek Singh ; Nibha…
• 关键词：2 ; 2-Bipyridine ; Kinetics ; Thermolysis ; Explosion delay ; Isothermal TG ; X ; ray crystallography
• 刊名：Journal of Thermal Analysis and Calorimetry
• 出版年：2015
• 出版时间：August 2015
• 年：2015
• 卷：121
• 期：2
• 页码：633-640
• 全文大小：611 KB
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  3.Kumar D, Kapoor IPS, Singh G, Goel N, Singh UP. Preparation, X-ray crystallography and thermolysis of transition metal nitrates of 2,2-bipyridine (part 63). J Therm Anal Calorim. 2012;107:325-4.View Article
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• 作者单位：Chandra Prakash Singh (1)
  Abhishek Singh (1)
  Nibha (2)
  Constantin G. Daniliuc (3)
  Bharat Kumar (4)
  Gurdip Singh (2)
  
  1. Department of Chemistry, D.B.S. College, Kanpur, 208006, India
  2. Chemistry Department, DDU Gorakhpur University, Gorakhpur, 273009, India
  3. Organisch-Chemisches Institut, Universit?t Münster, Münster, Germany
  4. Department of Chemistry, IIT, Delhi, 110016, India
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Sciences
  Polymer Sciences
  Physical Chemistry
  Inorganic Chemistry
  Measurement Science and Instrumentation
  
• 出版者：Akad茅miai Kiad贸, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic
• ISSN：1572-8943

文摘

The mixed-ligand mononuclear hexacoordinate cadmium perchlorate complex [Cd(2,2-bipy)2(H2O)(ClO4)]ClO4 was synthesized and characterized by FT-IR, elemental analysis and X-ray crystal structure determination. Thermal characteristics of the complex were studied by thermogravimetry (TG), differential thermal analysis and differential scanning calorimetry. The complex is stable at normal temperature and undergoes dehydration in between the temperature range 95-00?°C with loss of coordinated water (2.8?%). Thereafter, on increasing temperature, dehydrated complex shows some gradual mass loss followed by fast decomposition at higher temperature (265-80?°C). The kinetic parameters for the decomposition of the complex were investigated by applying model-fitting and isoconversional method on isothermal TG data recorded at five different temperatures. To explore the response of complex to sudden high heat, explosion delay time was recorded at five different temperatures, and kinetics of explosion was investigated using these data.