The synthesis and structure analysis of a novel polysiloxane-lanthanide hybrid material

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• 作者：Yan Liang ; Fang Yuan ; Yanmin Lu ; Haifeng Lu…
• 关键词：carboxyl ; terminated polysiloxane ; coordination ; fluorescence ; lanthanide ions ; luminescent materials
• 刊名：Russian Journal of Physical Chemistry A, Focus on Chemistry
• 出版年：2015
• 出版时间：September 2015
• 年：2015
• 卷：89
• 期：9
• 页码：1619-1624
• 全文大小：487 KB
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• 作者单位：Yan Liang (1)
  Fang Yuan (2)
  Yanmin Lu (1)
  Haifeng Lu (3)
  Shengyu Feng (3)
  
  1. School of Food and Bioengineering, Qilu University of Technology, Jinan, 250353, People鈥檚 Republic of China
  2. School of Chemistry and Pharmaceutical Engineering, Qilu University of Technology, Jinan, 250353, People鈥檚 Republic of China
  3. Key Laboratory of Special Functional Aggregated Materials, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, People鈥檚 Republic of China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Physical Chemistry
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1531-863X

文摘

The carboxyl-terminated polysiloxane (CTP) was successfully synthesized from amine-terminated polysiloxane and succinic anhydride and characterized by the 1H NMR and 13C NMR spectroscopy. The complexes of lanthanide ions (Eu3+, Tb3+, and Dy3+) with CTP were prepared and show excellent fluorescence properties. Narrow-width red or green fluorescence was observed under UV irradiation, indicating the successful coordination and the presence of the intra-molecular energy transfer process. For the functionalized polysiloxane, the coordination number is hard to be confirmed due to polysiloxane excellent flexibility. In order to investigate the coordination number and structure of these products, the carboxyl-functionalized disiloxane (CFD) and luminescent materials on its basis (CFD-Ln) were synthesized and their coordination structure was confirmed by IR, fluorescence spectroscopy and XPS. Through the qualitative comparison between the CFD-Ln and CTP-Ln, the coordination structure of the CTP-Ln material was elucidated.