Synthesis of complexing agents derived from ammonia and ethylene diamine and containing carboxyl and secondary amino groups

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• 作者：N. V. Tsirul’nikova ; O. N. Podmareva…
• 刊名：Russian Journal of General Chemistry
• 出版年：2015
• 出版时间：October 2015
• 年：2015
• 卷：85
• 期：10
• 页码：2482-2489
• 全文大小：296 KB
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• 作者单位：N. V. Tsirul’nikova (1)
  O. N. Podmareva (1)
  E. S. Dernovaya (1)
  T. S. Fetisova (1)
  M. M. Rodin (2)
  
  1. State Research Institute of Chemical Reagents and Special Purity Chemical Substances (IREA), ul. Bogorodskii val 3, Moscow, 107076, Russia
  2. Lomonosov Moscow State University of Fine Chemical Technologies, Moscow, Russia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Chemistry
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1608-3350

文摘

The synthesis of carboxyl-containing complexing agents derived from secondary amines as highly efficient reagents for solving specific problems in science, engineering, medicine, agriculture, and other fields is an urgent task in organic chemistry. Published data on the synthesis of such practically valuable compounds as ethylenediamine-N,N-diacetic (sym.EDDA), ethylenediamine-N,N-di-β-propionic acids (sym.ЕDDP), iminodiacetic (IDA), and iminodi-β-propionic (IDP) acids are symmarized. The latest achievements in the synthetic chemistry of carboxyl-containing complexing agents―ethylenediamine-N,N-di-β-propionic (as.ЕDDP) and a previously unknown new ethylenediamine-N-β-propionic (βEDMP) ЕDMP) acids―are presented. Original Russian Text ? N.V. Tsirul’nikova, O.N. Podmareva, E.S. Dernovaya, T.S. Fetisova, M.M. Rodin, 2014, published in Rossiiskii Khimicheskii Zhurnal, 2014, Vol. 58, No. 1, pp. 73-9.