Direct synthesis of mesoporous zeolite ETS-10 and Ni-ETS-10 with good catalytic performance in the Knoevenagel reaction

详细信息    查看全文

• 作者：Xiaojun Ni ; Mei Xiang ; Wenqian Fu ; Yuli Ma ; Pengyuan Zhu…
• 关键词：Mesoporous ETS ; 10 ; Basicity ; Knoevenagel condensation
• 刊名：Journal of Porous Materials
• 出版年：2016
• 出版时间：April 2016
• 年：2016
• 卷：23
• 期：2
• 页码：423-429
• 全文大小：2,083 KB
• 参考文献：1.S.M. Kuznicki, US Patent 4853202 (1989)
  2.M.W. Anderson, O. Terasaki, A. Philippou, S.P. Mackay, A. Ferreira, J. Rocha, S. Lidin, Nature 367, 347–351 (1994)CrossRef
  3.M.W. Anderson, O. Terasaki, T. Ohsuna, P.J.O. Malley, A. Philippou, S.P. Mackay, A. Ferreira, J. Rocha, S. Lidin, Philos. Mag. 84, 813–841 (1995)CrossRef
  4.M.E. Grillo, J. Carrazza, J. Phys. Chem. 100, 12261–12264 (1996)CrossRef
  5.L. Lv, F.B. Su, X.S. Zhao, Microporous Mesoporous Mater. 76, 113–122 (2004)CrossRef
  6.A. Philippou, M.W. Anderson, J. Catal. 189, 395–400 (2000)CrossRef
  7.S. Bernasconi, J.A. van Bokhoven, F. Krumeich, Microporous Mesoporous Mater. 66, 21–26 (2003)CrossRef
  8.C.S. Triantafillidis, A.G. Vlessidis, N.P. Evmiridis, Ind. Eng. Chem. Res. 39, 307–319 (2000)CrossRef
  9.J.C. Groen, T. Bach, U. Ziese, A.M. P-van Donk, K.P. de Jong, J.A. Moulijn, J. Pérez-Ramírez, J. Am. Chem. Soc. 127, 10792–10793 (2005)CrossRef
  10.J. Čejka, S. Mintova, Catal. Rev. 49, 457–509 (2007)CrossRef
  11.C.C. Pavel, W. Schmidt, Chem. Commun. 8, 882–884 (2006)CrossRef
  12.C.J.H. Jacobsen, C. Madsen, J. Houzvicka, I. Schmidt, A. Carlsson, J. Am. Chem. Soc. 122, 7116–7117 (2000)CrossRef
  13.J. Zhu, Y.H. Zhu, L.K. Zhu, M. Rigutto, A. van der Made, C.G. Yang, S.X. Pan, L. Wang, L.F. Zhu, Y.Y. Jin, Q. Sun, Q.M. Wu, X.J. Meng, D.L. Zhang, Y. Han, J.X. Li, Y.Y. Chu, A.M. Zheng, S.L. Qiu, X.M. Zheng, F.S. Xiao, J. Am. Chem. Soc. 136, 2503–2510 (2014)CrossRef
  14.M. Choi, R. Srivastava, R. Ryoo, Chem. Commun. 42, 4380–4382 (2006)CrossRef
  15.F.J. Liu, T. Willhammar, L. Wang, L.F. Zhu, Q. Sun, X.J. Meng, W. Carrillo-Cabrera, X.D. Zou, F.S. Xiao, J. Am. Chem. Soc. 134, 4557–4560 (2012)CrossRef
  16.W.Q. Fu, L. Zhang, T.D. Tang, Q.P. Ke, S. Wang, J.B. Hu, G.Y. Fang, J.X. Li, F.S. Xiao, J. Am. Chem. Soc. 133, 15346–15349 (2011)CrossRef
  17.Z.Z. Kang, G.Y. Fang, Q.P. Ke, J.B. Hu, T.D. Tang, ChemCatChem. 5, 2191–2194 (2013)CrossRef
  18.T.D. Tang, L. Zhang, W.Q. Fu, Y.L. Ma, J. Xu, J. Jiang, G.Y. Fang, F.S. Xiao, J. Am. Chem. Soc. 135, 11437–11440 (2013)CrossRef
  19.W.Q. Fu, T.T. Liu, Z.X. Fang, Y.L. Ma, X. Zheng, W.C. Wang, X.J. Ni, M.L. Hu, T.D. Tang, Chem. Commun. 51, 5890–5893 (2015)CrossRef
  20.M.V. Shankar, J. Ye, Catal. Commun. 11, 261–265 (2009)CrossRef
  21.N.C. Jeong, Y.J. Lee, K.B. Yoon, Microporous Mesoporous Mater. 115, 308–313 (2008)CrossRef
  22.B. Mihailova, V. Valtchev, S. Mintova, L. Konstantinov, Zeolites 16, 22–24 (1996)CrossRef
  23.G.X.S. Zhao, J.L. Lee, P.A. Chia, Langmuir 19, 1977–1979 (2003)CrossRef
  24.G. Bagnasco, M. Turco, G. Busca, T. Armaroli, A. Nastro, P.D. Luca, Adsorpt. Sci. Technol. 21, 683–696 (2003)CrossRef
  25.C.W. Park, S.T. Yang, W.S. Ahn, J. Porous Mater. 18, 133–138 (2011)CrossRef
  26.S. Ashtekar, A.M. Prakash, L. Kevan, L.F. Gladden, Chem. Commun. 1, 91–92 (1998)CrossRef
  27.P.D. Southon, R.F. Howe, Chem. Mater. 14, 4209–4218 (2002)CrossRef
  28.D. Barthomeuf, J. Phys. Chem. 88, 42–45 (1984)CrossRef
  29.J. Xie, M. Huang, S. Kaliaguine, Catal. Lett. 29, 281–291 (1994)CrossRef
  30.Y.C. Zhang, C.L. Chen, G.J. Wu, N.J. Guan, L.D. Li, J. Zhang, Chem. Commun. 50, 4305–4308 (2014)CrossRef
  31.Y. Yang, H.F. Yao, F.G. Xi, E.Q. Gao, J. Mol. Catal. A 390, 198–205 (2014)CrossRef
  32.M.E. Sloan, A. Staubitz, T.J. Clark, C.A. Russell, G.C. Lloyd-Jones, I. Manners, J. Am. Chem. Soc. 132, 3831–3841 (2010)CrossRef
  
• 作者单位：Xiaojun Ni (1)
  Mei Xiang (1)
  Wenqian Fu (1)
  Yuli Ma (1)
  Pengyuan Zhu (1)
  Wenchang Wang (1)
  Mingyang He (2)
  Keqin Yang (1)
  Jing Xiong (1)
  Tiandi Tang (1) (2)
  
  1. College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035, Zhejiang, People’s Republic of China
  2. Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, College of Petrochemical Engineering, Changzhou University, Changzhou, 213164, Jiangsu, People’s Republic of China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Characterization and Evaluation Materials
  Physical Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1573-4854

文摘

Developing highly active heterogeneous catalyst with strong basicity and porous structure is a highly attractive strategy for the base-catalyzed organic chemistry. Herein, we directly synthesized the mesoporous zeolite ETS-10 (METS-10) from using a water glass contained cationic copolymer with quaternary ammonium groups as a template. Furthermore, when the nickel nitrate solution was added into the starting synthesis gel, the nickel species facilitated the mesopore formation, and the Ni-containing mesoporous zeolite ETS-10 (Ni-METS-10) was obtained. Catalytic test results showed that the conversions of the benzaldehyde and citral over Ni-METS-10 (88.8 and 63.2 %) and METS-10 (85.5 and 60.1 %) catalysts are higher than those over both mesopore-free ETS-10 (77.3 and 47.7 %) and mesoporous NaX (MNaX, 55.0 and 35.2 %) catalysts in the condensation reactions with ethyl cyanoacetate. The higher activity of METS-10 and Ni-METS-10 than ETS-10 and MNaX is assigned to the fact that the strong basic sites on the catalysts can activate the reaction substrate and the mesoporous in the catalyst benefit the mass transfer and enhance the catalytic activity.