Synthesis and characterization of sustainable polyurethane based on epoxy soybean oil and modified by double-decker silsesquioxane

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• 作者：Jie Huang ; Pingping Jiang ; Xiaoting Li ; Yuandan Huang
• 刊名：Journal of Materials Science
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：51
• 期：5
• 页码：2443-2452
• 全文大小：1,039 KB
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• 作者单位：Jie Huang (1)
  Pingping Jiang (1)
  Xiaoting Li (1)
  Yuandan Huang (1)
  
  1. The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, 214122, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Materials Science
  Characterization and Evaluation Materials
  Polymer Sciences
  Continuum Mechanics and Mechanics of Materials
  Crystallography
  Mechanics
  
• 出版者：Springer Netherlands
• ISSN：1573-4803

文摘

A series of environmentally friendly and sustainable polyurethanes using epoxy soybean oil as feedstock were synthesized with the introduction of double-decker silsesquioxane. Feature is that through the two-step polymerization, double-decker octaphenylsilsesquioxanetetraol was added to partially replace 1,4-butanediol acting as chain extender, and petroleum-based polyol was effectively replaced for polyurethane synthesis. On top of that, POSS tetraol was prepared and characterized by 1H NMR and MALDI-TOF MS. As for the organic–inorganic hybrid nanocomposites, their structures and properties were investigated by FTIR, DSC, TGA, SEM, tensile test techniques, and static contact angle. DSC analysis showed that covalent incorporation of POSS into the PU network would increase the glass transition temperature (T _g) of the systems. TG analysis demonstrated that the hybrid nanocomposites were indeed more oxidative thermal stable, compared to virgin polyurethane especially at high temperature. SEM revealed that both nano- and micro-sized POSS aggregates were shown to be dispersed heterogeneously in the polyurethane matrix, despite the expectation to be dispersed or corporate into molecular chains by chemical bonding between OH and NCO. According to the tensile test results, POSS-containing nanocomposites exhibited an increased modulus with an increasing POSS concentration at low POSS content, and with high loading, these values would decline. The results of the static contact angles revealed that the hydrophobicity of the hybrid material was significantly improved with the inclusion of POSS.