Hollow click-based porous organic polymers for heterogenization of [Ru(bpy)3]2+ through electrostatic interactions

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• 作者：Liuyi Li ; Caiyan Cui ; Wenyue Su ; Yangxin Wang ; Ruihu Wang
• 关键词：porous organic polymers ; hollow ; heterogenization ; cationic metal complex ; catalysis
• 刊名：Nano Research
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：9
• 期：3
• 页码：779-786
• 全文大小：2,693 KB
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• 作者单位：Liuyi Li (1) (2)
  Caiyan Cui (2)
  Wenyue Su (1)
  Yangxin Wang (2)
  Ruihu Wang (2)
  
  1. State Key Laboratory of Photocatalysis on Energy and Environment, Fuzhou University, Fuzhou, 350002, China
  2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chinese Library of Science
  Chemistry
  Nanotechnology
  
• 出版者：Tsinghua University Press, co-published with Springer-Verlag GmbH
• ISSN：1998-0000

文摘

A facile approach for the heterogenization of transition metal catalysts using non-covalent interactions in hollow click-based porous organic polymers (H-CPPs) is presented. A catalytically active cationic species, [Ru(bpy)₃]2+ (bpy = 2,2’-bipyridyl), was immobilized in H-CPPs via electrostatic interactions. The intrinsic properties of [Ru(bpy)₃]2+ were well retained. The resulting Rucontaining hollow polymers exhibited excellent catalytic activity, enhanced stability, and good recyclability when used for the oxidative hydroxylation of 4-methoxyphenylboronic acid to 4-methoxyphenol under visible-light irradiation. The attractive catalytic performance mainly resulted from efficient mass transfer and the maintenance of the chemical properties of the cationic Ru complex in the H-CPPs.