Complex formation of MnII with tetra(p-tert-butyl)thiacalix[4]arene acid in aqueous solutions of surfactants and polymers

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• 作者：R. R. Amirov (1) <br> E. A. Burilova (1) <br> A. B. Ziyatdinova (1) <br> Yu. I. Zhuravleva (1) <br> I. I. Stoikov (1) <br> I. S. Antipin (1) <br>
• 关键词：p ; tert ; butylthiacalix[4]arene acid ; manganese(II) ; nuclear magnetic relaxation ; complex formation ; nonionogenic surfactants ; water ; soluble polymers
• 刊名：Russian Chemical Bulletin
• 出版年：2014
• 出版时间：January 2014
• 年：2014
• 卷：63
• 期：1
• 页码：207-213
• 全文大小：283 KB
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• 作者单位：R. R. Amirov (1) <br> E. A. Burilova (1) <br> A. B. Ziyatdinova (1) <br> Yu. I. Zhuravleva (1) <br> I. I. Stoikov (1) <br> I. S. Antipin (1) <br><br>1. Kazan Federal University, 18 ul. Kremlevskaya, 420008, Kazan, Russian Federation <br>
• ISSN：1573-9171

文摘

The formation of manganese(II) complexes with different stereoisomers of tetraacid based on p-tert-butylthiacalix[4]arene in water, in micellar solutions of nonionogenic surfactants, and in polymer solutions was studied. The formation of complexes with different degrees of ligand protonation was revealed by pH-metric titration and nuclear magnetic relaxation. On the basis of experimental data, the composition and stability constants of the solubilized complexes of stereoisomers of thiacalixarene acid with manganese(II) ions were determined using mathematical simulation methods. The manganese thiacalixarene complexes are unstable in solutions, especially upon the addition of calcium cations and in the presence of nitrilotriacetic acid.