Synthesis and characterization of water-soluble phthalocyanine Copper(II) complex and its coloration on acrylic fibers

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• 作者：Hak-Soo Kim ; Palanisamy Muthukumar ; Kyo-Sun Ku ; Young-A Son
• 关键词：Phthalocyanine ; Cationic dye ; Acrylic fiber ; Dyeing ; Colorimetric analysis
• 刊名：Fibers and Polymers
• 出版年：2015
• 出版时间：December 2015
• 年：2015
• 卷：16
• 期：12
• 页码：2552-2557
• 全文大小：817 KB
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• 作者单位：Hak-Soo Kim (1)
  Palanisamy Muthukumar (1)
  Kyo-Sun Ku (1)
  Young-A Son (1)
  
  1. Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University, Daejeon, 34134, Korea
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Polymer Sciences
  
• 出版者：The Korean Fiber Society
• ISSN：1875-0052

文摘

Herein, we report the synthesis and dyeing property of cationic copper phthalocyanine (cationic CuPc). The synthesized cationic CuPc was characterized using UV-Vis spectra and it showed good solubility in aqueous solution over a wide pH range. The dyeing of cationic CuPc was successfully employed onto acrylic fiber. The dyeing of acrylic fiber using cationic CuPc was achieved using conventional method. The effects of five important variables such as liquor ratio, dye concentration, dyeing time, temperature and pH were examined on the color strength (K/S) of dyed acrylic fiber. The maximum color strength was obtained at lower liquor ratio (100:1), higher dye concentration (6 %), longer dyeing time (60 min), 120 °C and alkaline condition (pH 11). Keywords Phthalocyanine Cationic dye Acrylic fiber Dyeing Colorimetric analysis