One-step synthesis of azole- and benzazole-based sulfonamides in aqueous media

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• 作者：Hassan Zali-Boeini (1)
  Zhaleh Najafi (1)
  Bahareh Abtahi (1)
  Hajar Golshadi Ghaleshahi (1)
  
  1. Department of Chemistry ; University of Isfahan ; 81746-73441 ; Isfahan ; Iran
  
• 关键词：Azoles ; Benzazoles ; Sulfonamides ; Heterocycles ; Green chemistry
• 刊名：Molecular Diversity
• 出版年：2015
• 出版时间：May 2015
• 年：2015
• 卷：19
• 期：2
• 页码：283-292
• 全文大小：781 KB
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• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Analytical Chemistry
  Polymer Sciences
  Organic Chemistry
  Pharmacy
  
• 出版者：Springer Netherlands
• ISSN：1573-501X

文摘

Several benzazoles (benzoxazoles, benzothiazoles, and benzimidazoles) and azoles (1 \(H\) -1,2,4-triazole-5(4 \(H\) )-thiones and 1,2,4-oxadiazoles) bearing a sulfonamide moiety were efficiently prepared via the reactions of dimethyl (arylsulfonyl) dithioimidocarbonate derivatives and their 2-aminobenzene precursors, thiosemicarbazides, and amidoximes, respectively, in the presence of \(\hbox {K}_{2}\hbox {CO}_{3}\) as a base in aqueous ethanol (25 %) as a green media in moderate to excellent yields.