Effect of the nature of a ligand on electrochemical characteristic of tin films in cycling in lithium-ion batteries

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• 作者：V. S. Kublanovsky ; V. N. Nikitenko ; N. I. Globa
• 刊名：Russian Journal of Applied Chemistry
• 出版年：2015
• 出版时间：March 2015
• 年：2015
• 卷：88
• 期：3
• 页码：407-412
• 全文大小：981 KB
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• 作者单位：V. S. Kublanovsky (1)
  V. N. Nikitenko (1)
  N. I. Globa (2)
  
  1. Vernadskii Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, pr. Akademika Palladina 32/34, Kiev, 03142, Ukraine
  2. Interagency Department of Electrochemical Power Engineering, National Academy of Sciences of Ukraine, bul. Akademika Vernadskogo 38A, Kiev, 03142, Ukraine
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Chemistry
  Industrial Chemistry and Chemical Engineering
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1608-3296

文摘

Potentiodynamic and galvanostatic cycling in 1 M ethylene carbonate-dimethyl carbonate solution of LiClO4 were used to study electrolytic tin films deposited from complex (tartrate, citrate, and citrate-trilonate) electrolytes. It was shown that the nature of a ligand strongly affects the electrochemical characteristics, specific capacity of tin films, and efficiency of their cycling in lithium power sources. The most stable charge-discharge characteristics are inherent in tin films deposited from the citrate electrolyte.