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Characterization of Group 5 dubnium homologs on diglycolamide extraction chromatography resins from nitric and hydrofluoric acid matrices
- 作者:J. D. Despotopulos (1) (2)
J. M. Gostic (3) M. E. Bennett (4) N. Gharibyan (1) R. A. Henderson (1) K. J. Moody (1) R. Sudowe (2) D. A. Shaughnessy (1)
- 关键词:Diglycolamide ; Extraction chromatography ; Heavy element ; Automation ; Dubnium
- 刊名:Journal of Radioanalytical and Nuclear Chemistry
- 出版年:2015
- 出版时间:January 2015
- 年:2015
- 卷:303
- 期:1
- 页码:485-494
- 全文大小:1,061 KB
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- 作者单位:J. D. Despotopulos (1) (2)
J. M. Gostic (3) M. E. Bennett (4) N. Gharibyan (1) R. A. Henderson (1) K. J. Moody (1) R. Sudowe (2) D. A. Shaughnessy (1)
1. Lawrence Livermore National Laboratory, 7000 East Ave, L-236, Livermore, CA, 94550, USA 2. University of Nevada-Las Vegas, 4505 South Maryland Parkway, Las Vegas, NV, 89154, USA 3. Airforce Technical Applications Center, Patrick Air Force Base, Brevard Country, FL, 32925, USA 4. Argonne National Laboratory, 9700 S. Cass Ave, Argonne, IL, 60439, USA
- 刊物类别:Chemistry and Materials Science
- 刊物主题:Chemistry
Nuclear Chemistry Physical Chemistry Nuclear Physics, Heavy Ions and Hadrons Diagnostic Radiology Inorganic Chemistry
- 出版者:Akad茅miai Kiad贸, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic
- ISSN:1588-2780
文摘
A diglycolamide-based resin was characterized for Group 5 (Ta, Nb and pseudo-homolog Pa) separation from Group 4 (Hf and Zr) and tri-valent actinides (Am). The batch uptake of the radionuclides of interest were determined for HNO3/HF matrices and the results were used to develop a column separation method that could be used for element 105 (Db) purification chemistry. Tantalum is significantly retained by the TODGA resin, while Pa/Nb show little to no retention. The affinity for Ta decreases as a function of increased [HNO3], while Zr/Hf (and Am) affinities increase under the same conditions. Adsorption of Ta to polypropylene vials and column frits became a significant focus of this work following several observations made during the course of the column separation method development. All of the Group 5 elements were separated from Group 4 and Am while Ta may be completely isolated from Nb/Pa with the TODGA resin with improvements in column parameters: column height and bed volume.
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