X-ray study of [Cu(NH3)4](ReO4)2-[Cu(NH3)2(μ-ReO _{详细信息    查看全文}

• 作者：S. A. Gromilov ; A. P. Tyutyunnik ; D. A. Piryazev…
• 关键词：copper ; perrhenate ; thermolysis ; powder X ; ray diffraction analysis ; single crystal X ; ray diffraction analysis ; crystal chemistry
• 刊名：Journal of Structural Chemistry
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：57
• 期：1
• 页码：140-145
• 全文大小：415 KB
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  5.P. E. Plyusnin Synthesis and Physico-Chemical Studies of Complexes of Tetrachlorometallates of Pd(II), Pt(II) and Au(III) [in Russian], Cand. Sci. (Chem.) Dissertation Theses, Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk (2009).
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• 作者单位：S. A. Gromilov (1) (2)
  A. P. Tyutyunnik (3)
  D. A. Piryazev (1) (2)
  P. E. Plyusnin (1) (2)
  S. V. Korenev (1) (2)
  
  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
  2. Novosibirsk National Research State University, Novosibirsk, Russia
  3. Institute of Solid State Chemistry, Urals Branch, Russian Academy of Sciences, Ekaterinburg, Russia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Inorganic Chemistry
  Physical Chemistry
  Atoms, Molecules, Clusters and Plasmas
  Atomic and Molecular Structure and Spectra
  Solid State Physics and Spectroscopy
  Russian Library of Science
  
• 出版者：Springer New York
• ISSN：1573-8779

文摘

The X-ray in-situ study of [Cu(NH₃)₄](ReO₄)₂ complex salt is carried out on heating up to 500 K. The product obtained at this temperature is a new crystalline phase [Cu(NH₃)₂(μ-ReO₄)₂] _n with the following unit cell parameters: a = 14.7523(3) Å, b = 5.8559(1) Å, c = 5.6290(1) Å, β = 111.387(1)°, V = = 452.799(2) Å3, space group C2/m, Z = 2, d _x = 4.386 g/cm3. The coordination polyhedron of the Cu atom is a distorted octahedron formed by two nitrogen atoms (Cu–N 2.195 Å), and four oxygen atoms (Cu–О 2.306 Å). The structure consists of infinite [Cu(NH₃)₂(μ-ReO₄)₂] _n chains, the shortest N(H)…O distances between the chains being 2.82 Å.