Thiocarbamide derivatives of europium, holmium, and erbium iodides: Synthesis and structures

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• 作者：T. A. Antonenko (1)
  L. Yu. Alikberova (1)
  D. V. Albov (2)
  N. S. Rukk (1) roukkn@inbox.ru
• 刊名：Russian Journal of Coordination Chemistry
• 出版年：2011
• 出版时间：October 2011
• 年：2011
• 卷：37
• 期：10
• 页码：785-790
• 全文大小：540.5 KB
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• 作者单位：1. Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 119571 Russia2. Moscow State University, Leninskie gory, Moscow, 119992 Russia
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Physical Chemistry
  Inorganic Chemistry
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1608-3318

文摘

Data on the synthesis, IR spectra, and X-ray diffraction analysis of the thiocarbamide complexes of europium, holmium, and erbium iodides, [Ln(H₂O)₉]I₃ · 2CS(NH₂)₂ (Ln = Eu (I), Ho(II), Er (III)), are presented. The crystal structures of the complexes contain nonaaqualanthanide cations (the polyhedron shape is a monocapped tetragonal antiprism), outer-sphere thiocarbamide molecules, and uncoordinated iodide ions. The thiocarbamide molecules form hydrogen bonds with the aqua cations and join them into continuous layers or network ensembles. The thiocarbamide molecules are disordered in the crystal structures of complexes II and III.