A novel biocompatible magnetic iron oxide nanoparticles/hydrogel based on poly (acrylic acid) grafted onto starch for controlled drug release

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• 作者：Ghasem Rezanejade Bardajee ; Zari Hooshyar
• 关键词：Magnetic iron oxide nanoparticles ; Hydrogel ; Starch ; Drug release
• 刊名：Journal of Polymer Research
• 出版年：2013
• 出版时间：November 2013
• 年：2013
• 卷：20
• 期：11
• 全文大小：1198KB
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• 作者单位：Ghasem Rezanejade Bardajee (1)
  Zari Hooshyar (1)
  
  1. Department of Chemistry, Payame Noor University, PO BOX 19395-3697, Tehran, Iran
  
• ISSN：1572-8935

文摘

In this paper, a novel biocompatible magnetic iron oxide nanoparticles/hydrogel was synthesized based on the simultaneous formation of magnetic iron oxide nanoparticles (MION) and hydrogel based on poly (acrylic acid) grafted onto starch (PAA-g-starch). The structural, morphological and magnetic properties of the optimized sample were characterized by scanning electron microscopy with energy dispersive X-ray analysis (SEM–EDAX), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), thermal gravimetric analysis (TGA), and vibrating sample magnetometer (VSM). In addition, the effect of external magnetic field (EMF), pH, and temperature on the swelling of the MION-PAA-g-starch hydrogel was studied. The results showed that the EMF reduced the swelling capacity of MION-PAA-g-starch hydrogel. Moreover, the in vitro release of deferasirox was studied in pH = 2 and 7 under EMF. The release curves were nicely fitted by the Korsemeyer–Peppas equation and the release followed by non-Fickian diffusion.