Effect of Al2O3 nanowires on the electrochemical properties of di-ureasil-based organic–inorganic hybrid electrolytes

详细信息    查看全文

• 作者：Yian-Yuan Chu ; Zong-Ying Liu ; Diganta Saikia ; Chieh-Ju Chou ; Hsien-Ming Kao…
• 关键词：Organic–inorganic hybrid electrolyte ; Ionic conductivity ; Thermal analysis ; Electrochemical stability
• 刊名：Ionics
• 出版年：2015
• 出版时间：September 2015
• 年：2015
• 卷：21
• 期：9
• 页码：2523-2534
• 全文大小：1,222 KB
• 参考文献：1.Kim DG, Shim J, Lee JH, Kwon SJ, Baik JH, Lee JC (2013) Preparation of solid-state composite electrolytes based on organic/inorganic hybrid star-shaped polymer and PEG-functionalized POSS for all-solid-state lithium battery applications. Polymer 54:5812-820CrossRef
  2.Kwon W, Chang YJ, Park YC, Jang HM, Rhee SW (2012) A light scattering polymer gel electrolyte for high performance dye-sensitized solar cells. J Mater Chem 22:6027-031CrossRef
  3.Lee ASS, Lee JH, Lee JC, Hong SM, Hwang SS, Koo CM (2014) Novel polysilsesquioxane hybrid polymer electrolytes for lithium ion batteries. J Mater Chem A 2:1277-283
  4.Sim LN, Majid SR, Arof AK (2012) Characteristics of PEMA/PVdF-HFP blend polymeric gel films incorporated with lithium triflate salt in electrochromic device. Solid State Ionics 209-10:15-3CrossRef
  5.Caruso T, Capoleoni S, Cazzanelli E, Agostino RG, Villano P, Passerini S (2002) Characterization of PEO-lithium triflate polymer electrolytes: conductivity, DSC and Raman investigations. Ionics 8:36-3CrossRef
  6.Lim YJ, An YH, Jo NJ (2012) Polystyrene-Al2O3 composite solid polymer electrolyte for lithium secondary battery. Nanoscale Res Lett 19:19 (1-strong class="EmphasisTypeBold">6)CrossRef
  7.Karan NK, Pradhan DK, Thomas R, Natesan B, Katiyar RS (2008) Solid polymer electrolytes based on polyethylene oxide and lithium trifluoromethane sulfonate (PEO–LiCF3SO3): ionic conductivity and dielectric relaxation. Solid State Ionics 179:689-96CrossRef
  8.Zhang J, Huang X, Wei H, Fu J, Liu W, Tang X (2011) Preparation and electrochemical behaviors of composite solid polymer electrolytes based on polyethylene oxide with active inorganic–organic hybrid polyphosphazene nanotubes as fillers. New J Chem 35:614-21CrossRef
  9.Wang S, Min K (2010) Solid polymer electrolytes of blends of polyurethane and polyether modified polysiloxane and their ionic conductivity. Polymer 51:2621-628CrossRef
  10.Fenton DE, Parker JM, Wright PV (1973) Complexes of alkali metal ions with poly(ethylene oxide). Polymer 14:589CrossRef
  11.Armand MB, Chabagno JM, Duclot MJ (1979) Polyethers as solid electrolytes. In: Vashista P, Mundy JN, Shenoy GK (eds) Fast ion transport in solids: electrodes and electrolytes. North Holland, Amsterdam, pp 131-36
  12.Angell CA (1992) Mobile ions in amorphous solids. Annu Rev Phys Chem 43:693-17CrossRef
  13.Ren T, Huang XB, Zhao X, Tang XZ (2003) The effects of salt concentration on ion state and conductivity in comb cross-linked polymer electrolytes. J Mater Sci 38:3007-011CrossRef
  14.Ding J, Chuy C, Holdcroft S (2002) Solid polymer electrolytes based on ionic graft polymers: effect of graft chain length on nano-structured, ionic networks. Adv Funct Mater 12:389-94CrossRef
  15.Wang Y, Ma X, Zhang Q, Tian N (2010) Synthesis and properties of gel polymer electrolyte membranes based on novel comb-like methyl methacrylate copolymers. J Membr Sci 349:279-86CrossRef
  16.Hou WH, Chen CY, Wang CC, Huang YH (2003) The effect of different lithium salts on conductivity of comb-like polymer electrolyte with chelating functional group. Electrochim Acta 48:679-90CrossRef
  17.Li J, Khan IM (1993) Highly conductive solid polymer electrolytes prepared by blending high molecular weight poly(ethylene oxide), poly(2- or 4-vinylpyridine), and lithium perchlorate. Macromolecules 26:4544-550CrossRef
  18.Croce F, Appetechi GB, Persi L, Scrosati B (1998) Nanocomposite polymer electrolytes for lithium batteries. Nature 394:456-58CrossRef
  19.Praveen D, Bhat SV, Damle R (2013) Role of silica nanoparticles in conductivity enhancement of nanocomposite solid polymer electrolytes: (PEGx NaBr): ySiO2. Ionics 19:1375-379CrossRef
  20.Bronstein LM, Karlinsey RL, Ritter K, Joo CG, Stein B, Zwanziger JW (2004) Design of organic–inorganic solid polymer electrolytes: synthesis, structure, and properties. J Mater Chem 14:1812-820CrossRef
  21.Tigelaar DM, Meador MAB, Kinder JD, Bennett WR (2006) New APTES cross-linked polymers from poly(ethylene oxide)s and cyanuric chloride for lithium batteries. Macromolecules 39:120-27CrossRef
  22.Ferreira CB, Fernandes M, Rodrigues LC, Silva MM, Smith MJ, de Zea Bermudez V (2013) Vibrational analysis of d-PCL(530)/siloxane-based hybrid electrolytes doped with two lithium salts. Ionics 19:1803-809CrossRef
  23.Kao HM, Chao SW, Chang PC (2006) Multinuclear solid-state NMR, self-diffusion coefficients, differential scanning calorimetry, and ionic conductivity of solid organic–inorganic hybrid electrolytes based on PPG ?PEG ?PPG diamine, siloxane, and lithium perchlorate. Macromolecules 39:1029-040CrossRef
  24.de Zea Bermudez V, Poinsignon C, Armand MB (1997) Chemistry and physical properties of sulfamide and its derivatives: proton conducting materials. J Mater Chem 7:1677-692CrossRef
  25.Brik ME, Titman JJ, Bayle JP, Judeinstein P (1996) Mapping of motional heterogeneity in organic-inorganic nanocomposite gels. J Polym
• 作者单位：Yian-Yuan Chu (1)
  Zong-Ying Liu (1)
  Diganta Saikia (1)
  Chieh-Ju Chou (1)
  Hsien-Ming Kao (1)
  Ming-Chou Chen (1)
  
  1. Department of Chemistry, National Central University, Chung-Li, 32054, Taiwan, Republic of China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Electrochemistry
  Materials Science
  Physical Chemistry
  Condensed Matter
  Renewable Energy Sources
  Electrical Power Generation and Transmission
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1862-0760

文摘

Organic–inorganic hybrid electrolytes based on the reaction of triblock copolymer poly(propylene glycol)-block-poly(ethylene glycol)-block-poly(propylene glycol) bis(2-aminopropyl ether) and 3-(triethoxysilyl)propyl isocyanate doped with lithium trifluoromethanesulfonate and Al₂O₃ nanowires were synthesized by a sol–gel process. The structural and electrochemical properties of the materials thus obtained were systematically investigated by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry, thermogravimetric analysis, powder X-ray diffraction, 29Si CPMAS (cross-polarization magic angle spinning) NMR, alternate current impedance, and linear sweep voltammetry measurements. FTIR spectra showed the occurrence of complexation and interaction among the components. The maximum ionic conductivity values of 9.8?×-0? S cm? and 6.8?×-0? S cm? were obtained at 30 and 75 °C, respectively, for the solid hybrid electrolyte with a [O]/[Li] ratio of 16 and 1 wt% of Al₂O₃ nanowires. A Vogel–Tamman–Fulcher-like temperature dependence of ionic conductivity was observed for the hybrid electrolytes doped with fillers. The electrochemical stability window of ~4.0 V makes the organic–inorganic hybrid electrolyte promising for lithium-ion battery application at low voltages. Keywords Organic–inorganic hybrid electrolyte Ionic conductivity Thermal analysis Electrochemical stability