Equilibrium and kinetic Si isotope fractionation factors and their implications for Si isotope distributions in the Earth’s surface environments

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• 作者：Hong-tao He ; Siting Zhang ; Chen Zhu ; Yun Liu
• 关键词：Si isotopes ; Equilibrium fractionation factor ; Quantum chemistry calculation ; Cluster model ; Kinetic isotope effect
• 刊名：Chinese Journal of Geochemistry
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：35
• 期：1
• 页码：15-24
• 全文大小：1,504 KB
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• 作者单位：Hong-tao He (1) (2)
  Siting Zhang (1)
  Chen Zhu (3)
  Yun Liu (1)
  
  1. State Key Laboratory of Ore Deposit Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, 550081, China
  2. University of Chinese Academy of Sciences, Beijing, 100049, China
  3. Department of Geological Sciences, Indiana University, Bloomington, IN, 47405, USA
  
• 刊物主题：Geochemistry;
• 出版者：SP Science Press
• ISSN：1993-0364

文摘

Several important equilibrium Si isotope fractionation factors among minerals, organic molecules and the H₄SiO₄ solution are complemented to facilitate the explanation of the distributions of Si isotopes in Earth’s surface environments. The results reveal that, in comparison to aqueous H₄SiO₄, heavy Si isotopes will be significantly enriched in secondary silicate minerals. On the contrary, quadra-coordinated organosilicon complexes are enriched in light silicon isotope relative to the solution. The extent of 28Si-enrichment in hyper-coordinated organosilicon complexes was found to be the largest. In addition, the large kinetic isotope effect associated with the polymerization of monosilicic acid and dimer was calculated, and the results support the previous statement that highly 28Si-enrichment in the formation of amorphous quartz precursor contributes to the discrepancy between theoretical calculations and field observations. With the equilibrium Si isotope fractionation factors provided here, Si isotope distributions in many of Earth’s surface systems can be explained. For example, the change of bulk soil δ30Si can be predicted as a concave pattern with respect to the weathering degree, with the minimum value where allophane completely dissolves and the total amount of sesqui-oxides and poorly crystalline minerals reaches their maximum. When, under equilibrium conditions, the well-crystallized clays start to precipitate from the pore solutions, the bulk soil δ30Si will increase again and reach a constant value. Similarly, the precipitation of crystalline smectite and the dissolution of poorly crystalline kaolinite may explain the δ30Si variations in the ground water profile. The equilibrium Si isotope fractionations among the quadra-coordinated organosilicon complexes and the H₄SiO₄ solution may also shed light on the Si isotope distributions in the Si-accumulating plants. Keywords Si isotopes Equilibrium fractionation factor Quantum chemistry calculation Cluster model Kinetic isotope effect