Determination of critical micelle concentrations of ionic and nonionic surfactants based on relative viscosity measurements by capillary electrophoresis

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• 作者：Chunhung Wu (1)
  Neng Jia Li (1)
  Kuan Cheng Chen (1)
  Hsiu-Fu Hsu (1)
  
• 关键词：Critical micelle concentration ; Surfactant ; Capillary electrophoresis ; Relative viscosity
• 刊名：Research on Chemical Intermediates
• 出版年：2014
• 出版时间：July 2014
• 年：2014
• 卷：40
• 期：6
• 页码：2371-2379
• 全文大小：
• 参考文献：1. T.F. Tadros, / Applied Surfactants: Principles and Applications, 1st edn. (Wiley, Weinheim, 2005), pp. 1-6 CrossRef
  2. E. Calvo, R. Bravo, A. Amigo, J. Gracia-Fadrique, Fluid Phase Equilib. 282, 14 (2009) CrossRef
  3. E. Fuguet, C. Rafols, M. Roses, E. Bosch, Anal. Chim. Acta 548, 95 (2005) CrossRef
  4. U. Anand, C. Jash, S. Mukherjee, J. Colloid Interface Sci. 364, 400 (2011) CrossRef
  5. R.E. Stark, P.D. Leff, S.G. Milheim, A. Kropf, J. Phys. Chem. 88, 6063 (1984) CrossRef
  6. C.-E. Lin, J. Chromatogr. A 1037, 467 (2004) CrossRef
  7. M.S. Bello, R. Rezzonico, P.G. Righetti, J. Chromatogr. A 659, 199 (1994) CrossRef
  8. S. Priyanto, G.A. Mansoori, A. Suwono, Chem. Eng. Sci. 56, 6933 (2001) CrossRef
  9. F.E. Stanley, A.M. Warner, E. Schneiderman, A.M. Stalcup, J. Chromatogr. A 1216, 8431 (2009) CrossRef
  10. E. Cordova, J. Gao, G.M. Whitesides, Anal. Chem. 69, 1370 (1997) CrossRef
  11. A. Imhof, A. van Blaaderen, G. Maret, J. Mellema, J.K.G. Dhont, J. Chem. Phys. 100, 2170 (1994) CrossRef
  12. M.A. Lauffer, J. Am. Chem. Soc. 66, 1188 (1944) CrossRef
  13. A. Evilevitch, V. Lobaskin, U. Olsson, P. Linse, P. Schurtenberger, Langmuir 17, 1043 (2001) CrossRef
  14. H. Chen, Y. Ding, Y. He, C. Tan, Chem. Phys. Lett. 444, 333 (2007) CrossRef
  15. M.L. Corrin, W.D. Harkins, J. Am. Chem. Soc. 69, 683 (1947) CrossRef
  16. L. Xu, E. Yokoyama, M. Satoh, Langmuir 21, 7153 (2005) CrossRef
  17. M.J. Schick, J. Phys. Chem. 68, 3585 (1964) CrossRef
  18. M. Abu-Hamdiyyah, K.J. Kumari, Phys. Chem. 94, 6445 (1990) CrossRef
  19. J.C. Jacquier, P.L. Desbene, J. Chromatogr. A 718, 167 (1995) CrossRef
  20. G. Mangiapia, D. Berti, P. Baglioni, J. Teixeira, L. Paduano, J. Phys. Chem. B 108, 9772 (2004) CrossRef
  21. L.V. Dearden, E.M. Woolley, J. Chem. Thermodyn. 28, 1283 (1996) CrossRef
  22. B. Lindman, N. Kamenka, M.-C. Puyal, B. Brun, B. Jonsson, J. Phys. Chem. 88, 53 (1984) CrossRef
  23. A. Gonzalez-Perez, J.M. Ruso, G. Prieto, F. Sarmiento, Colloid Polym. Sci. 282, 1133 (2004) CrossRef
  24. M.F. Emerson, A. Holtzer, J. Phys. Chem. 69, 3718 (1965) CrossRef
  25. R. Sabate, M. Gallardo, J. Estelrich, Electrophoresis 21, 481 (2000) CrossRef
  26. A.K. Singh, M. Darshi, S. Kanvah, J. Phys. Chem. A 104, 464 (2000) CrossRef
  27. A. Zdziennicka, K. Szymczyk, J. Krawczyk, B. Janczuk, Fluid Phase Equilib. 322-23, 126 (2012) CrossRef
  28. A. Chattopadhyay, K.G. Harikumar, FEBS Lett. 391, 199 (1996) CrossRef
  29. Q. Guan, S.D. Noblitt, C.S. Henry, Electrophoresis 33, 379 (2012) CrossRef
  30. J.C. Gertsch, S.D. Noblitt, D.M. Cropek, C.S. Henry, Anal. Chem. 82, 3426 (2010) CrossRef
  31. B. Rozycka-Roszak, P. Misiak, B. Jurczak, K.A. Wilk, J. Phys. Chem. B 112, 16546 (2008) CrossRef
  32. A. Vishnyakov, M.-T. Lee, A.V. Neimark, J. Phys. Chem. Lett. 4, 797 (2013) CrossRef
  33. C. Wu, T. Liu, B. Chu, Macromolecules 30, 4574 (1997) CrossRef
  34. P. Alexandridus, J.F. Holzwarth, T.A. Hatton, Macromolecules 27, 2414 (1994) CrossRef
  35. T. Zemb, M. Drifford, M. Hayoun, A. Jehanno, J. Phys. Chem. 87, 4524 (1983) CrossRef
  36. E. Ruckenstein, R. Nagarajan, J. Phys. Chem. 85, 3010 (1981) CrossRef
  37. M.A. Desando, L.W. Reeves, Can. J. Chem. 64, 1817 (1986) CrossRef
  38. G.K. Batchelor, J.T. Green, J. Fluid Mech. 56, 401 (1972) CrossRef
  39. P. Ekwall, P. Holmberg, Acta Chem. Scand. 19, 455 (1965) CrossRef
  40. L. Moreira, A. Firoozabadi, Langmuir 26, 15177 (2010) CrossRef
  
• 作者单位：Chunhung Wu (1)
  Neng Jia Li (1)
  Kuan Cheng Chen (1)
  Hsiu-Fu Hsu (1)
  
  1. Department of Chemistry, Tamkang University, 151 Yingchuan Road, Tamsui Dist., New Taipei City, 25137, Taiwan
  
• ISSN：1568-5675

文摘

The critical micelle concentration (CMC) can be obtained by measuring the distinct physical properties of surfactant molecules in the monomeric and micellar states. In this study, two linear increments of relative viscosity with distinct slopes were obtained when increasing surfactant concentrations from dilute solution to above the CMC, which was then determined by the intersection of the two linear extrapolations. Using a capillary electrophoresis (CE) instrument and Poiseuille’s law, the viscosities of surfactants at a series of concentrations covering the monomeric and micellar regions could be obtained by measuring the hydrodynamic flow rates of the corresponding surfactant solutions. We applied this method to determine the CMC values of various types of surfactants including anionic, cationic, zwitterionic, and nonionic surfactants. The resulting CMC values were all in good agreement with those reported in literature. Using this method, the multiple-stage micellization process of a short-chain surfactant was revealed. We have also demonstrated that the CE-based viscometer was applicable to the study of CMC variation caused by organic or electrolyte additives.