Catalytic application of metallic iron from the dyeing sludge ash for benzene steam reforming reaction in tar emitted from biomass gasification

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• 作者：Sung-Bang Nam ; Yeong-Su Park ; Yong-Sik Yun…
• 关键词：Biomass Gasification ; Steam Reforming ; Catalytic Tar Reduction ; Iron Oxide Catalyst ; Benzene
• 刊名：Korean Journal of Chemical Engineering
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：33
• 期：2
• 页码：465-472
• 全文大小：313 KB
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• 作者单位：Sung-Bang Nam (1)
  Yeong-Su Park (1)
  Yong-Sik Yun (1)
  Jae-Hoi Gu (1)
  Ho-Jin Sung (1)
  Masayuki Horio (2)
  
  1. Plant Engineering Center, Institute for Advanced Engineering, 633-2, Goan, Baegam, Cheoin, Yongin, Kyeonggi, Seoul, 449-863, Korea
  2. Department of Chemical Engineering, Graduate School of Bio-Applications and Systems Engineering, Tokyo University of Agriculture and Technology, 24-16, Naka-cho 2, Koganei-shi, Tokyo, 184-8588, Japan
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Industrial Chemistry and Chemical Engineering
  Catalysis
  Materials Science
  Biotechnology
  
• 出版者：Springer New York
• ISSN：1975-7220

文摘

Because it is the most promising method for reforming tar in a gasification system, a catalytic steam reforming reaction of tar using a dyeing sludge ash catalyst that contains mostly iron oxide has been modeled using benzene to investigate whether a steam reforming catalyst produced from waste is viable. The catalytic activity of the ash catalyst is similar to that of the commercially available iron-chrome-based catalyst for the same equivalent total amount of Fe₂O₃. The activity over the ash catalyst has been examined in terms of the weight hour space velocity (WHSV) and the reaction temperature to develop a model for the reaction kinetics. Using a power law model, the reaction order coefficients of the benzene and steam were estimated to be 0.43 and 0, respectively. The activation energy required for the ash catalyst was approximately 187.6 kJ mol−1. In addition, the reductive properties of the iron oxide in the ash catalyst were also examined via XRD and H₂-TPR analyses. Keywords Biomass Gasification Steam Reforming Catalytic Tar Reduction Iron Oxide Catalyst Benzene