Hydrogen Intercalation of Graphene and Boron Nitride Monolayers Grown on Pt(111)

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• 作者：Mingming Wei ; Qiang Fu ; Hao Wu ; Aiyi Dong ; Xinhe Bao
• 关键词：Graphene ; Hexagonal boron nitride ; Pt(111) ; Intercalation ; Photoemission spectroscopy
• 刊名：Topics in Catalysis
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：59
• 期：5-7
• 页码：543-549
• 全文大小：1,849 KB
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• 作者单位：Mingming Wei (1)
  Qiang Fu (1)
  Hao Wu (1) (2)
  Aiyi Dong (1)
  Xinhe Bao (1)
  
  1. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian, 116023, People’s Republic of China
  2. Department of Chemical Physics, University of Science and Technology of China, Hefei, 230026, People’s Republic of China
  
• 刊物主题：Catalysis; Physical Chemistry; Pharmacy; Industrial Chemistry/Chemical Engineering; Characterization and Evaluation of Materials;
• 出版者：Springer US
• ISSN：1572-9028

文摘

H₂ atmosphere is often involved in growth and application of two-dimensional (2D) atomic crystals, and it is of great importance to understand interaction of the 2D materials with H₂ molecules. Here, a full graphene layer and a full hexagonal boron nitride (h-BN) layer grown on Pt(111) were exposed to H₂ atmosphere, which were investigated by in situ near ambient pressure X-ray photoelectron spectroscopy and quasi in situ ultraviolet photoelectron spectroscopy. We confirm the occurrence of hydrogen intercalation of the graphene and h-BN overlayers in ambient pressure H₂. The hydrogen intercalation in 0.1 Torr H₂ at room temperature and hydrogen desorption in 0.1 Torr H₂ at 200 °C are fully reversible on the graphene/Pt(111) and h-BN/Pt(111) surfaces. Furthermore, hydrogen desorption on the graphene/Pt(111) and h-BN/Pt(111) surfaces was found to happen at lower temperature than that on the Pt(111) surface due to the graphene and h-BN cover effect.