A Novel Coumarin-Based Fluorescent Probe for the Detection of Hydrazine Both in Aqueous Solution and Vapor State

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• 作者：Yu-Hao Xiao ; Gang Xi ; Xuan-Xuan Zhao ; Shuai Zhou ; Ze-Quan Zhou…
• 关键词：Coumarin ; Fluorescent probe ; Hydrazine ; Aqueous solution ; Vapour state
• 刊名：Journal of Fluorescence
• 出版年：2015
• 出版时间：July 2015
• 年：2015
• 卷：25
• 期：4
• 页码：1023-1029
• 全文大小：1,820 KB
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• 作者单位：Yu-Hao Xiao (1)
  Gang Xi (1)
  Xuan-Xuan Zhao (1)
  Shuai Zhou (1)
  Ze-Quan Zhou (1)
  Bao-Xiang Zhao (1)
  
  1. Institute of Organic Chemistry, School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, People’s Republic of China
  
• 刊物类别：Biomedical and Life Sciences
• 刊物主题：Biomedicine
  Biomedicine
  Biophysics and Biomedical Physics
  Biotechnology
  Biochemistry
  Analytical Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1573-4994

文摘

A novel coumarin-based fluorescent probe CF was synthesized for the detection of hydrazine both in aqueous solution and vapor state with high sensitivity and selectivity. Upon addition of hydrazine, the solution of probe CF in MeCN-H2O (3/7, v/v, buffered CH3COOH/CH3COONa) at pH?5.0 exhibited a remarkable change in emission color from pale green to light blue, which could be recognized with naked eyes. Applied in weak acid condition, probe CF could detect hydrazine selectively with large amount of unknown environments according to the competing tests. Besides, with the limit of detection 8.32?ppb (2.6?×-0? M), probe CF could well meet the request (10?ppb) of the U.S. Environmental Protection Agency (EPA).